Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates

[Image: see text] A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C–C and C–N bond formation. It is entirely a new strategy to produce enecarbam...

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Autores principales: Reddy, Chatrala Ravikumar, Sridhar, Balasubramanian, V. Subba Reddy, Basi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644781/
https://www.ncbi.nlm.nih.gov/pubmed/31459104
http://dx.doi.org/10.1021/acsomega.8b01118
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author Reddy, Chatrala Ravikumar
Sridhar, Balasubramanian
V. Subba Reddy, Basi
author_facet Reddy, Chatrala Ravikumar
Sridhar, Balasubramanian
V. Subba Reddy, Basi
author_sort Reddy, Chatrala Ravikumar
collection PubMed
description [Image: see text] A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C–C and C–N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner.
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spelling pubmed-66447812019-08-27 Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates Reddy, Chatrala Ravikumar Sridhar, Balasubramanian V. Subba Reddy, Basi ACS Omega [Image: see text] A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C–C and C–N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner. American Chemical Society 2018-08-22 /pmc/articles/PMC6644781/ /pubmed/31459104 http://dx.doi.org/10.1021/acsomega.8b01118 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Reddy, Chatrala Ravikumar
Sridhar, Balasubramanian
V. Subba Reddy, Basi
Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
title Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
title_full Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
title_fullStr Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
title_full_unstemmed Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
title_short Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
title_sort ru(ii)-catalyzed oxidative functionalization of arylhydrazine-1,2-dicarboxylates with internal alkynes for the synthesis of enecarbamates
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644781/
https://www.ncbi.nlm.nih.gov/pubmed/31459104
http://dx.doi.org/10.1021/acsomega.8b01118
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