New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate

[Image: see text] The access to free, unsolvated ions at high concentrations and ambient temperatures enabled by ionic liquids results in previously unobserved reactivity for even well-studied ions, demonstrated here by acetate ([OAc](−)) acting as a reducing agent for B(10)H(14) but only when used...

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Autores principales: Kelley, Steven P., Rachiero, Giovanni P., Titi, Hatem M., Rogers, Robin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644799/
https://www.ncbi.nlm.nih.gov/pubmed/31458977
http://dx.doi.org/10.1021/acsomega.8b00775
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author Kelley, Steven P.
Rachiero, Giovanni P.
Titi, Hatem M.
Rogers, Robin D.
author_facet Kelley, Steven P.
Rachiero, Giovanni P.
Titi, Hatem M.
Rogers, Robin D.
author_sort Kelley, Steven P.
collection PubMed
description [Image: see text] The access to free, unsolvated ions at high concentrations and ambient temperatures enabled by ionic liquids results in previously unobserved reactivity for even well-studied ions, demonstrated here by acetate ([OAc](−)) acting as a reducing agent for B(10)H(14) but only when used as a neat liquid in [C(2)mim][OAc] at ambient temperature. More typical reaction products are obtained when B(10)H(14) is reacted with [C(2)mim][OAc] at an elevated temperature or in the presence of strong bases.
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spelling pubmed-66447992019-08-27 New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate Kelley, Steven P. Rachiero, Giovanni P. Titi, Hatem M. Rogers, Robin D. ACS Omega [Image: see text] The access to free, unsolvated ions at high concentrations and ambient temperatures enabled by ionic liquids results in previously unobserved reactivity for even well-studied ions, demonstrated here by acetate ([OAc](−)) acting as a reducing agent for B(10)H(14) but only when used as a neat liquid in [C(2)mim][OAc] at ambient temperature. More typical reaction products are obtained when B(10)H(14) is reacted with [C(2)mim][OAc] at an elevated temperature or in the presence of strong bases. American Chemical Society 2018-08-01 /pmc/articles/PMC6644799/ /pubmed/31458977 http://dx.doi.org/10.1021/acsomega.8b00775 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Kelley, Steven P.
Rachiero, Giovanni P.
Titi, Hatem M.
Rogers, Robin D.
New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
title New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
title_full New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
title_fullStr New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
title_full_unstemmed New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
title_short New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
title_sort new reactions for old ions: cage rearrangements, hydrolysis, and two-electron reduction of nido-decaborane in neat 1-ethyl-3-methylimidazolium acetate
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644799/
https://www.ncbi.nlm.nih.gov/pubmed/31458977
http://dx.doi.org/10.1021/acsomega.8b00775
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