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New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of nido-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate
[Image: see text] The access to free, unsolvated ions at high concentrations and ambient temperatures enabled by ionic liquids results in previously unobserved reactivity for even well-studied ions, demonstrated here by acetate ([OAc](−)) acting as a reducing agent for B(10)H(14) but only when used...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644799/ https://www.ncbi.nlm.nih.gov/pubmed/31458977 http://dx.doi.org/10.1021/acsomega.8b00775 |