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All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology

[Image: see text] A Prussian blue LiFeFe(CN)(6) thin-film cathode is fabricated by a nonvacuum coating technology without post-annealing process. The thin film of the solid electrolyte lithium phosphorus oxynitride (LiPON) is deposited onto the cathode by using radio-frequency magnetron sputtering....

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Autores principales: Shi, Ding-Ren, Fu, Jing, Shadike, Zulipiya, Cao, Ming-Hui, Wang, Wei-Wen, Fu, Zheng-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644809/
https://www.ncbi.nlm.nih.gov/pubmed/31458915
http://dx.doi.org/10.1021/acsomega.8b01102
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author Shi, Ding-Ren
Fu, Jing
Shadike, Zulipiya
Cao, Ming-Hui
Wang, Wei-Wen
Fu, Zheng-Wen
author_facet Shi, Ding-Ren
Fu, Jing
Shadike, Zulipiya
Cao, Ming-Hui
Wang, Wei-Wen
Fu, Zheng-Wen
author_sort Shi, Ding-Ren
collection PubMed
description [Image: see text] A Prussian blue LiFeFe(CN)(6) thin-film cathode is fabricated by a nonvacuum coating technology without post-annealing process. The thin film of the solid electrolyte lithium phosphorus oxynitride (LiPON) is deposited onto the cathode by using radio-frequency magnetron sputtering. Then, the lithium metal anode is deposited on the LiPON film by the thermal evaporation method to fabricate the all-solid-state LiFeFe(CN)(6)/LiPON/Li battery with a thickness of 16 μm and a size of ∼10 cm(2). Electrochemical properties of LiFeFe(CN)(6)/LiPON/Li battery are first investigated at various temperatures from −30 to 80 °C. Our results demonstrated that the all-solid-state LiFeFe(CN)(6)/LiPON/Li battery exhibits a discharge capacity of 82.5 mA h/g for the third cycle at 60 °C and shows stable cyclic performance within 200 cycles. These results provide the feasibility to assemble an all-solid-state lithium-ion battery by combining nonvacuum and vacuum techniques through an environmentally friendly process at low temperature.
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spelling pubmed-66448092019-08-27 All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology Shi, Ding-Ren Fu, Jing Shadike, Zulipiya Cao, Ming-Hui Wang, Wei-Wen Fu, Zheng-Wen ACS Omega [Image: see text] A Prussian blue LiFeFe(CN)(6) thin-film cathode is fabricated by a nonvacuum coating technology without post-annealing process. The thin film of the solid electrolyte lithium phosphorus oxynitride (LiPON) is deposited onto the cathode by using radio-frequency magnetron sputtering. Then, the lithium metal anode is deposited on the LiPON film by the thermal evaporation method to fabricate the all-solid-state LiFeFe(CN)(6)/LiPON/Li battery with a thickness of 16 μm and a size of ∼10 cm(2). Electrochemical properties of LiFeFe(CN)(6)/LiPON/Li battery are first investigated at various temperatures from −30 to 80 °C. Our results demonstrated that the all-solid-state LiFeFe(CN)(6)/LiPON/Li battery exhibits a discharge capacity of 82.5 mA h/g for the third cycle at 60 °C and shows stable cyclic performance within 200 cycles. These results provide the feasibility to assemble an all-solid-state lithium-ion battery by combining nonvacuum and vacuum techniques through an environmentally friendly process at low temperature. American Chemical Society 2018-07-10 /pmc/articles/PMC6644809/ /pubmed/31458915 http://dx.doi.org/10.1021/acsomega.8b01102 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Shi, Ding-Ren
Fu, Jing
Shadike, Zulipiya
Cao, Ming-Hui
Wang, Wei-Wen
Fu, Zheng-Wen
All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology
title All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology
title_full All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology
title_fullStr All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology
title_full_unstemmed All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology
title_short All-Solid-State Rechargeable Lithium Metal Battery with a Prussian Blue Cathode Prepared by a Nonvacuum Coating Technology
title_sort all-solid-state rechargeable lithium metal battery with a prussian blue cathode prepared by a nonvacuum coating technology
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644809/
https://www.ncbi.nlm.nih.gov/pubmed/31458915
http://dx.doi.org/10.1021/acsomega.8b01102
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