Lanthanide(III)-Based Single-Ion Magnets

[Image: see text] Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the discovery of SIM properties in a bis-(phthalocyaninato)lanthanide complex. A recent report on [Dy(Cp(ttt))(2)][BC(6)F(5)] indicating that it exhibits the highest known blocking temperature (60 K) h...

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Autores principales: Dey, Atanu, Kalita, Pankaj, Chandrasekhar, Vadapalli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644820/
https://www.ncbi.nlm.nih.gov/pubmed/31459081
http://dx.doi.org/10.1021/acsomega.8b01204
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author Dey, Atanu
Kalita, Pankaj
Chandrasekhar, Vadapalli
author_facet Dey, Atanu
Kalita, Pankaj
Chandrasekhar, Vadapalli
author_sort Dey, Atanu
collection PubMed
description [Image: see text] Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the discovery of SIM properties in a bis-(phthalocyaninato)lanthanide complex. A recent report on [Dy(Cp(ttt))(2)][BC(6)F(5)] indicating that it exhibits the highest known blocking temperature (60 K) has spurred fresh interest in this area. In this article, we discuss about the various requirements of lanthanide-based SIMs along with representative examples. Specifically, we describe the complexes whose coordination numbers vary from 2 to 8. We also discuss the representative examples of organometallic lanthanide complexes that can function as molecular magnets.
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spelling pubmed-66448202019-08-27 Lanthanide(III)-Based Single-Ion Magnets Dey, Atanu Kalita, Pankaj Chandrasekhar, Vadapalli ACS Omega [Image: see text] Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the discovery of SIM properties in a bis-(phthalocyaninato)lanthanide complex. A recent report on [Dy(Cp(ttt))(2)][BC(6)F(5)] indicating that it exhibits the highest known blocking temperature (60 K) has spurred fresh interest in this area. In this article, we discuss about the various requirements of lanthanide-based SIMs along with representative examples. Specifically, we describe the complexes whose coordination numbers vary from 2 to 8. We also discuss the representative examples of organometallic lanthanide complexes that can function as molecular magnets. American Chemical Society 2018-08-20 /pmc/articles/PMC6644820/ /pubmed/31459081 http://dx.doi.org/10.1021/acsomega.8b01204 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Dey, Atanu
Kalita, Pankaj
Chandrasekhar, Vadapalli
Lanthanide(III)-Based Single-Ion Magnets
title Lanthanide(III)-Based Single-Ion Magnets
title_full Lanthanide(III)-Based Single-Ion Magnets
title_fullStr Lanthanide(III)-Based Single-Ion Magnets
title_full_unstemmed Lanthanide(III)-Based Single-Ion Magnets
title_short Lanthanide(III)-Based Single-Ion Magnets
title_sort lanthanide(iii)-based single-ion magnets
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644820/
https://www.ncbi.nlm.nih.gov/pubmed/31459081
http://dx.doi.org/10.1021/acsomega.8b01204
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AT kalitapankaj lanthanideiiibasedsingleionmagnets
AT chandrasekharvadapalli lanthanideiiibasedsingleionmagnets

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