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Biocompatible and Light-Penetrating Hydrogels for Water Decontamination

[Image: see text] Solar light-activated photocatalyst nanoparticles (NPs) are promising environment-friendly low cost tools for water decontamination, but their dispersion in the environment must be minimized. Here, we propose the incorporation of TiO(2)-NPs (also in combination with graphene platel...

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Autores principales: Guidetti, Gloria, Giuri, Demetra, Zanna, Nicola, Calvaresi, Matteo, Montalti, Marco, Tomasini, Claudia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644841/
https://www.ncbi.nlm.nih.gov/pubmed/31458948
http://dx.doi.org/10.1021/acsomega.8b01037
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author Guidetti, Gloria
Giuri, Demetra
Zanna, Nicola
Calvaresi, Matteo
Montalti, Marco
Tomasini, Claudia
author_facet Guidetti, Gloria
Giuri, Demetra
Zanna, Nicola
Calvaresi, Matteo
Montalti, Marco
Tomasini, Claudia
author_sort Guidetti, Gloria
collection PubMed
description [Image: see text] Solar light-activated photocatalyst nanoparticles (NPs) are promising environment-friendly low cost tools for water decontamination, but their dispersion in the environment must be minimized. Here, we propose the incorporation of TiO(2)-NPs (also in combination with graphene platelets) into highly biocompatible hydrogels as a promising approach for the production of photoactive materials for water treatment. We also propose a convenient fluorescence-based method to investigate the hydrogel photocatalytic activity in real time with a conventional fluorimeter. Kinetics analysis of the degradation profile of a target fluorescent model pollutant demonstrates that fast degradation occurs in the matrix bulk. Fluorescence anisotropy proved that small pollutant molecules diffuse freely in the hydrogel. Rheological and scanning electron microscopy characterization showed that the TiO(2)-NP incorporation does not significantly alter the hydrogel mechanical and morphological properties.
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spelling pubmed-66448412019-08-27 Biocompatible and Light-Penetrating Hydrogels for Water Decontamination Guidetti, Gloria Giuri, Demetra Zanna, Nicola Calvaresi, Matteo Montalti, Marco Tomasini, Claudia ACS Omega [Image: see text] Solar light-activated photocatalyst nanoparticles (NPs) are promising environment-friendly low cost tools for water decontamination, but their dispersion in the environment must be minimized. Here, we propose the incorporation of TiO(2)-NPs (also in combination with graphene platelets) into highly biocompatible hydrogels as a promising approach for the production of photoactive materials for water treatment. We also propose a convenient fluorescence-based method to investigate the hydrogel photocatalytic activity in real time with a conventional fluorimeter. Kinetics analysis of the degradation profile of a target fluorescent model pollutant demonstrates that fast degradation occurs in the matrix bulk. Fluorescence anisotropy proved that small pollutant molecules diffuse freely in the hydrogel. Rheological and scanning electron microscopy characterization showed that the TiO(2)-NP incorporation does not significantly alter the hydrogel mechanical and morphological properties. American Chemical Society 2018-07-19 /pmc/articles/PMC6644841/ /pubmed/31458948 http://dx.doi.org/10.1021/acsomega.8b01037 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Guidetti, Gloria
Giuri, Demetra
Zanna, Nicola
Calvaresi, Matteo
Montalti, Marco
Tomasini, Claudia
Biocompatible and Light-Penetrating Hydrogels for Water Decontamination
title Biocompatible and Light-Penetrating Hydrogels for Water Decontamination
title_full Biocompatible and Light-Penetrating Hydrogels for Water Decontamination
title_fullStr Biocompatible and Light-Penetrating Hydrogels for Water Decontamination
title_full_unstemmed Biocompatible and Light-Penetrating Hydrogels for Water Decontamination
title_short Biocompatible and Light-Penetrating Hydrogels for Water Decontamination
title_sort biocompatible and light-penetrating hydrogels for water decontamination
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644841/
https://www.ncbi.nlm.nih.gov/pubmed/31458948
http://dx.doi.org/10.1021/acsomega.8b01037
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