Oxidized Carbon Black as an Activator of Transesterification Reactions under Solvent-Free Conditions

[Image: see text] A metal-free procedure for oxidation of carbon black (CB), under mild and ecofriendly conditions, is described. The procedure, based on 5/1 w/w H(2)O(2)/H(2)SO(4), when applied to high-surface-area CB, leads to oxidation contents (O/C = 0.66) comparable to those obtained for graphi...

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Detalles Bibliográficos
Autores principales: Acocella, Maria Rosaria, Maggio, Mario, Ambrosio, Chiara, Aprea, Noemi, Guerra, Gaetano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644938/
https://www.ncbi.nlm.nih.gov/pubmed/31457343
http://dx.doi.org/10.1021/acsomega.7b01007
Descripción
Sumario:[Image: see text] A metal-free procedure for oxidation of carbon black (CB), under mild and ecofriendly conditions, is described. The procedure, based on 5/1 w/w H(2)O(2)/H(2)SO(4), when applied to high-surface-area CB, leads to oxidation contents (O/C = 0.66) comparable to those obtained for graphite with the more aggressive and metal-based Hummers method (O/C 0.63). Oxidized nanocarbons are able to activate transesterification reactions under solvent-free conditions. Activation of transesterification reactions is much more effective by oxidized CB than by graphene oxide.

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