Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide

[Image: see text] An efficient and facile method for the synthesis of trifluoromethylthiolated 5-hydroxy-1H-pyrazole derivatives by reaction of pyrazolin-5-ones with trifluoromethanesulfenamide (PhNHSCF(3)) in the presence of BiCl(3) was developed.

Detalles Bibliográficos
Autores principales: Liu, Qingyun, Huang, Tao, Zhao, Xianghu, Wu, Jingjing, Cao, Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645000/
https://www.ncbi.nlm.nih.gov/pubmed/31457332
http://dx.doi.org/10.1021/acsomega.7b01453
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author Liu, Qingyun
Huang, Tao
Zhao, Xianghu
Wu, Jingjing
Cao, Song
author_facet Liu, Qingyun
Huang, Tao
Zhao, Xianghu
Wu, Jingjing
Cao, Song
author_sort Liu, Qingyun
collection PubMed
description [Image: see text] An efficient and facile method for the synthesis of trifluoromethylthiolated 5-hydroxy-1H-pyrazole derivatives by reaction of pyrazolin-5-ones with trifluoromethanesulfenamide (PhNHSCF(3)) in the presence of BiCl(3) was developed.
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spelling pubmed-66450002019-08-27 Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide Liu, Qingyun Huang, Tao Zhao, Xianghu Wu, Jingjing Cao, Song ACS Omega [Image: see text] An efficient and facile method for the synthesis of trifluoromethylthiolated 5-hydroxy-1H-pyrazole derivatives by reaction of pyrazolin-5-ones with trifluoromethanesulfenamide (PhNHSCF(3)) in the presence of BiCl(3) was developed. American Chemical Society 2017-11-09 /pmc/articles/PMC6645000/ /pubmed/31457332 http://dx.doi.org/10.1021/acsomega.7b01453 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Liu, Qingyun
Huang, Tao
Zhao, Xianghu
Wu, Jingjing
Cao, Song
Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
title Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
title_full Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
title_fullStr Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
title_full_unstemmed Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
title_short Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
title_sort bismuth(iii)-promoted trifluoromethylthiolation of pyrazolin-5-ones with trifluoromethanesulfenamide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645000/
https://www.ncbi.nlm.nih.gov/pubmed/31457332
http://dx.doi.org/10.1021/acsomega.7b01453
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