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Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
[Image: see text] The sulfenylation of the vinyl C–H bond in ketene dithioacetals leading to the synthesis of polythiolated alkenes is achieved via the promotion of molecular iodine. In addition, alkyl thiols also exhibit tolerance to the C–H bond elaboration reaction for the synthesis of correspond...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645039/ https://www.ncbi.nlm.nih.gov/pubmed/31459275 http://dx.doi.org/10.1021/acsomega.8b01946 |
| Sumario: | [Image: see text] The sulfenylation of the vinyl C–H bond in ketene dithioacetals leading to the synthesis of polythiolated alkenes is achieved via the promotion of molecular iodine. In addition, alkyl thiols also exhibit tolerance to the C–H bond elaboration reaction for the synthesis of corresponding alkylthiolated ketene dithioacetals. |
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