Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes

[Image: see text] The sulfenylation of the vinyl C–H bond in ketene dithioacetals leading to the synthesis of polythiolated alkenes is achieved via the promotion of molecular iodine. In addition, alkyl thiols also exhibit tolerance to the C–H bond elaboration reaction for the synthesis of correspond...

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Autores principales: Deng, Leiling, Liu, Yunyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645039/
https://www.ncbi.nlm.nih.gov/pubmed/31459275
http://dx.doi.org/10.1021/acsomega.8b01946
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author Deng, Leiling
Liu, Yunyun
author_facet Deng, Leiling
Liu, Yunyun
author_sort Deng, Leiling
collection PubMed
description [Image: see text] The sulfenylation of the vinyl C–H bond in ketene dithioacetals leading to the synthesis of polythiolated alkenes is achieved via the promotion of molecular iodine. In addition, alkyl thiols also exhibit tolerance to the C–H bond elaboration reaction for the synthesis of corresponding alkylthiolated ketene dithioacetals.
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spelling pubmed-66450392019-08-27 Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes Deng, Leiling Liu, Yunyun ACS Omega [Image: see text] The sulfenylation of the vinyl C–H bond in ketene dithioacetals leading to the synthesis of polythiolated alkenes is achieved via the promotion of molecular iodine. In addition, alkyl thiols also exhibit tolerance to the C–H bond elaboration reaction for the synthesis of corresponding alkylthiolated ketene dithioacetals. American Chemical Society 2018-09-25 /pmc/articles/PMC6645039/ /pubmed/31459275 http://dx.doi.org/10.1021/acsomega.8b01946 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Deng, Leiling
Liu, Yunyun
Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
title Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
title_full Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
title_fullStr Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
title_full_unstemmed Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
title_short Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
title_sort metal-free vinyl c–h sulfenylation/alkyl thiolation of ketene dithioacetals for the synthesis of polythiolated alkenes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645039/
https://www.ncbi.nlm.nih.gov/pubmed/31459275
http://dx.doi.org/10.1021/acsomega.8b01946
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AT liuyunyun metalfreevinylchsulfenylationalkylthiolationofketenedithioacetalsforthesynthesisofpolythiolatedalkenes

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