Theoretical Study on DBU-Catalyzed Insertion of Isatins into Aryl Difluoronitromethyl Ketones: A Case for Predicting Chemoselectivity Using Electrophilic Parr Function

[Image: see text] The possible mechanisms of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed chemoselective insertion of N-methyl isatin into aryl difluoronitromethyl ketone to synthesize 3,3-disubstituted and 2,2-disubstituted oxindoles have been studied in this work. As revealed by calculated r...

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Detalles Bibliográficos
Autores principales: Li, Xue, Wei, Donghui, Li, Zhongjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645149/
https://www.ncbi.nlm.nih.gov/pubmed/31457285
http://dx.doi.org/10.1021/acsomega.7b00907

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645149/
https://www.ncbi.nlm.nih.gov/pubmed/31457285
http://dx.doi.org/10.1021/acsomega.7b00907

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