Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide

[Image: see text] Small, “doll”-shaped tetracyanocyclopentadienide bearing a 1,3-dioxane acetal “head” and cyano “hands” and “feet” was synthesized. Its pyridinium salt, which was named NanoGoblin, exhibited catalytic activity in the methanolysis of acetals, as demonstrated by the reaction with Nano...

Descripción completa

Detalles Bibliográficos
Autores principales: Sakai, Takeo, Nagao, Yoshihiro, Nakamura, Yuki, Mori, Yuji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645318/
https://www.ncbi.nlm.nih.gov/pubmed/31457390
http://dx.doi.org/10.1021/acsomega.7b01748
_version_ 1783437438682660864
author Sakai, Takeo
Nagao, Yoshihiro
Nakamura, Yuki
Mori, Yuji
author_facet Sakai, Takeo
Nagao, Yoshihiro
Nakamura, Yuki
Mori, Yuji
author_sort Sakai, Takeo
collection PubMed
description [Image: see text] Small, “doll”-shaped tetracyanocyclopentadienide bearing a 1,3-dioxane acetal “head” and cyano “hands” and “feet” was synthesized. Its pyridinium salt, which was named NanoGoblin, exhibited catalytic activity in the methanolysis of acetals, as demonstrated by the reaction with NanoKid in methanol-d(4), where the acetal head of NanoKid was converted to a deuterated dimethyl acetal moiety.
format Online
Article
Text
id pubmed-6645318
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-66453182019-08-27 Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide Sakai, Takeo Nagao, Yoshihiro Nakamura, Yuki Mori, Yuji ACS Omega [Image: see text] Small, “doll”-shaped tetracyanocyclopentadienide bearing a 1,3-dioxane acetal “head” and cyano “hands” and “feet” was synthesized. Its pyridinium salt, which was named NanoGoblin, exhibited catalytic activity in the methanolysis of acetals, as demonstrated by the reaction with NanoKid in methanol-d(4), where the acetal head of NanoKid was converted to a deuterated dimethyl acetal moiety. American Chemical Society 2017-11-30 /pmc/articles/PMC6645318/ /pubmed/31457390 http://dx.doi.org/10.1021/acsomega.7b01748 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Sakai, Takeo
Nagao, Yoshihiro
Nakamura, Yuki
Mori, Yuji
Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide
title Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide
title_full Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide
title_fullStr Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide
title_full_unstemmed Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide
title_short Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide
title_sort methanolysis of the cyclic acetal function of nanokid catalyzed by nanogoblin, the pyridinium salt of tetracyanocyclopentadienide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645318/
https://www.ncbi.nlm.nih.gov/pubmed/31457390
http://dx.doi.org/10.1021/acsomega.7b01748
work_keys_str_mv AT sakaitakeo methanolysisofthecyclicacetalfunctionofnanokidcatalyzedbynanogoblinthepyridiniumsaltoftetracyanocyclopentadienide
AT nagaoyoshihiro methanolysisofthecyclicacetalfunctionofnanokidcatalyzedbynanogoblinthepyridiniumsaltoftetracyanocyclopentadienide
AT nakamurayuki methanolysisofthecyclicacetalfunctionofnanokidcatalyzedbynanogoblinthepyridiniumsaltoftetracyanocyclopentadienide
AT moriyuji methanolysisofthecyclicacetalfunctionofnanokidcatalyzedbynanogoblinthepyridiniumsaltoftetracyanocyclopentadienide

Ejemplares similares