Effect of the Fabrication Technique on the Thermoelectric Performance of Mg-Based Compounds—A Case Study of n-Type Mg(2)Ge

[Image: see text] High performance, low cost, and low toxicity have been the main characteristics associated with magnesium-based thermoelectric materials. Nevertheless, the high volatility of magnesium creates challenges in the synthesis of these materials. In this work, n-type Mg(2)Ge is synthesized using a solid-state technique, fully characterized, and compared with Mg(2)Ge fabricated through different processes. We have found that Bi is an ineffective dopant in Mg(2)Ge and precipitates into Mg(2)Bi(3). Regardless of the technique used, the loss of Mg by evaporation and formation of precipitates in Bi-doped samples resulted in a low charge carrier concentration and, consequently, a low power factor. The precipitates significantly reduced the lattice thermal conductivity, however, leading to a figure-of-merit, zT, of 0.4 at 725 K, improving the previously reported figure-of-merit, zT, of 0.2 for Sb-doped Mg(2)Ge. This work highlights the impact of the fabrication technique on the thermoelectric performance of Mg-based compounds.