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Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol

[Image: see text] A combinative effect of two or more individual material properties, such as lattice parameters and chemical properties, has been well-known to generate novel nanomaterials with special crystal growth behavior and physico-chemical performance. This paper reports unusually high catal...

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Detalles Bibliográficos
Autores principales: Mawarnis, Elvy Rahmi, Ali Umar, Akrajas, Tomitori, Masahiko, Balouch, Aamna, Nurdin, Muhammad, Muzakkar, Muhammad Zakir, Oyama, Munetaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645377/
https://www.ncbi.nlm.nih.gov/pubmed/31459253
http://dx.doi.org/10.1021/acsomega.8b01268
Descripción
Sumario:[Image: see text] A combinative effect of two or more individual material properties, such as lattice parameters and chemical properties, has been well-known to generate novel nanomaterials with special crystal growth behavior and physico-chemical performance. This paper reports unusually high catalytic performance of AgPt nanoferns in the hydrogenation reaction of acetone conversion to isopropanol, which is several orders higher compared to the performance shown by pristine Pt nanocatalysts or other metals and metal–metal oxide hybrid catalyst systems. It has been demonstrated that the combinative effect during the bimetallisation of Ag and Pt produced nanostructures with a highly anisotropic morphology, i.e., hierarchical nanofern structures, which provide high-density active sites on the catalyst surface for an efficient catalytic reaction. The extent of the effect of structural growth on the catalytic performance of hierarchical AgPt nanoferns is discussed.