Cargando…

Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol

[Image: see text] A combinative effect of two or more individual material properties, such as lattice parameters and chemical properties, has been well-known to generate novel nanomaterials with special crystal growth behavior and physico-chemical performance. This paper reports unusually high catal...

Descripción completa

Detalles Bibliográficos
Autores principales: Mawarnis, Elvy Rahmi, Ali Umar, Akrajas, Tomitori, Masahiko, Balouch, Aamna, Nurdin, Muhammad, Muzakkar, Muhammad Zakir, Oyama, Munetaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645377/
https://www.ncbi.nlm.nih.gov/pubmed/31459253
http://dx.doi.org/10.1021/acsomega.8b01268
_version_ 1783437451632574464
author Mawarnis, Elvy Rahmi
Ali Umar, Akrajas
Tomitori, Masahiko
Balouch, Aamna
Nurdin, Muhammad
Muzakkar, Muhammad Zakir
Oyama, Munetaka
author_facet Mawarnis, Elvy Rahmi
Ali Umar, Akrajas
Tomitori, Masahiko
Balouch, Aamna
Nurdin, Muhammad
Muzakkar, Muhammad Zakir
Oyama, Munetaka
author_sort Mawarnis, Elvy Rahmi
collection PubMed
description [Image: see text] A combinative effect of two or more individual material properties, such as lattice parameters and chemical properties, has been well-known to generate novel nanomaterials with special crystal growth behavior and physico-chemical performance. This paper reports unusually high catalytic performance of AgPt nanoferns in the hydrogenation reaction of acetone conversion to isopropanol, which is several orders higher compared to the performance shown by pristine Pt nanocatalysts or other metals and metal–metal oxide hybrid catalyst systems. It has been demonstrated that the combinative effect during the bimetallisation of Ag and Pt produced nanostructures with a highly anisotropic morphology, i.e., hierarchical nanofern structures, which provide high-density active sites on the catalyst surface for an efficient catalytic reaction. The extent of the effect of structural growth on the catalytic performance of hierarchical AgPt nanoferns is discussed.
format Online
Article
Text
id pubmed-6645377
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-66453772019-08-27 Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol Mawarnis, Elvy Rahmi Ali Umar, Akrajas Tomitori, Masahiko Balouch, Aamna Nurdin, Muhammad Muzakkar, Muhammad Zakir Oyama, Munetaka ACS Omega [Image: see text] A combinative effect of two or more individual material properties, such as lattice parameters and chemical properties, has been well-known to generate novel nanomaterials with special crystal growth behavior and physico-chemical performance. This paper reports unusually high catalytic performance of AgPt nanoferns in the hydrogenation reaction of acetone conversion to isopropanol, which is several orders higher compared to the performance shown by pristine Pt nanocatalysts or other metals and metal–metal oxide hybrid catalyst systems. It has been demonstrated that the combinative effect during the bimetallisation of Ag and Pt produced nanostructures with a highly anisotropic morphology, i.e., hierarchical nanofern structures, which provide high-density active sites on the catalyst surface for an efficient catalytic reaction. The extent of the effect of structural growth on the catalytic performance of hierarchical AgPt nanoferns is discussed. American Chemical Society 2018-09-20 /pmc/articles/PMC6645377/ /pubmed/31459253 http://dx.doi.org/10.1021/acsomega.8b01268 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Mawarnis, Elvy Rahmi
Ali Umar, Akrajas
Tomitori, Masahiko
Balouch, Aamna
Nurdin, Muhammad
Muzakkar, Muhammad Zakir
Oyama, Munetaka
Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol
title Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol
title_full Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol
title_fullStr Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol
title_full_unstemmed Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol
title_short Hierarchical Bimetallic AgPt Nanoferns as High-Performance Catalysts for Selective Acetone Hydrogenation to Isopropanol
title_sort hierarchical bimetallic agpt nanoferns as high-performance catalysts for selective acetone hydrogenation to isopropanol
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645377/
https://www.ncbi.nlm.nih.gov/pubmed/31459253
http://dx.doi.org/10.1021/acsomega.8b01268
work_keys_str_mv AT mawarniselvyrahmi hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol
AT aliumarakrajas hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol
AT tomitorimasahiko hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol
AT balouchaamna hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol
AT nurdinmuhammad hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol
AT muzakkarmuhammadzakir hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol
AT oyamamunetaka hierarchicalbimetallicagptnanofernsashighperformancecatalystsforselectiveacetonehydrogenationtoisopropanol