Room-Temperature Activation of CO(2) by Dual Defect-Stabilized Nanoscale Hematite (Fe(2−δ)O(3–v)): Concurrent Role of Fe and O Vacancies

[Image: see text] We demonstrate that synthetically controlled concurrent stabilization of Fe and O vacancy defects on the surface of interbraided nanoscale hematite (Fe(2−δ)O(3–v)) renders an interesting surface chemistry which can reduce CO(2) to CO at room temperature (RT). Importantly, we realized a highly enhanced output of 410 μmol h(–1) g(–1) at RT, as compared to that of 10 μmol h(–1) g(–1) for bulk hematite. It is argued based on the activity degradation under cycling and first principles density functional theory calculations that the excess chemical energy embedded in the defect-stabilized surface is expended in this high-energy conversion process, which leads to progressive filling up of oxygen vacancies.