Probing the Structural and Electronic Effects on the Origin of π-Facial Stereoselectivity in 1-Methylphosphole 1-Oxide Cycloadditions and Cyclodimerization

[Image: see text] We have examined the π-facial stereoselectivity in the Diels–Alder reactions of phosphole oxides computationally. The experimentally observed syn-cycloadditions have been rationalized with the Cieplak model and distortion–interaction model. The natural bond orbital analysis suggest...

Descripción completa

Detalles Bibliográficos
Autores principales: Bhai, Surjit, Jana, Kalyanashis, Ganguly, Bishwajit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645475/
https://www.ncbi.nlm.nih.gov/pubmed/31459205
http://dx.doi.org/10.1021/acsomega.8b01165

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645475/
https://www.ncbi.nlm.nih.gov/pubmed/31459205
http://dx.doi.org/10.1021/acsomega.8b01165

Ejemplares similares