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Probing the Structural and Electronic Effects on the Origin of π-Facial Stereoselectivity in 1-Methylphosphole 1-Oxide Cycloadditions and Cyclodimerization

[Image: see text] We have examined the π-facial stereoselectivity in the Diels–Alder reactions of phosphole oxides computationally. The experimentally observed syn-cycloadditions have been rationalized with the Cieplak model and distortion–interaction model. The natural bond orbital analysis suggest...

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Detalles Bibliográficos
Autores principales:	Bhai, Surjit, Jana, Kalyanashis, Ganguly, Bishwajit
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645475/ https://www.ncbi.nlm.nih.gov/pubmed/31459205 http://dx.doi.org/10.1021/acsomega.8b01165

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