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Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes

[Image: see text] A nanocomposite of polyaniline with graphitic carbon nitride (GCN) nanosheets has been synthesized by a facile oxidative polymerization of an aniline monomer and GCN to demonstrate its potential to catalyze the synthesis of various indole-substituted 4H-chromenes. The synthesized n...

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Autores principales: Bahuguna, Ashish, Choudhary, Priyanka, Chhabra, Tripti, Krishnan, Venkata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645668/
https://www.ncbi.nlm.nih.gov/pubmed/31459291
http://dx.doi.org/10.1021/acsomega.8b01687
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author Bahuguna, Ashish
Choudhary, Priyanka
Chhabra, Tripti
Krishnan, Venkata
author_facet Bahuguna, Ashish
Choudhary, Priyanka
Chhabra, Tripti
Krishnan, Venkata
author_sort Bahuguna, Ashish
collection PubMed
description [Image: see text] A nanocomposite of polyaniline with graphitic carbon nitride (GCN) nanosheets has been synthesized by a facile oxidative polymerization of an aniline monomer and GCN to demonstrate its potential to catalyze the synthesis of various indole-substituted 4H-chromenes. The synthesized nanocomposite was thoroughly characterized using different spectroscopic techniques to confirm the morphology and composition. Subsequently, the fabricated nanocomposite was used as a heterogeneous catalyst to synthesize several bioactive indole-substituted 4H-chromenes in an aqueous medium. Organic transformation under benign and environmentally sustainable conditions is of paramount importance in the view of growing environmental pollution. Water is the universal Green solvent and has been a preferred choice of nature to perform various reactions. The catalyst developed in this work showed very good recyclability and adaptability for the synthesis of various medicinally significant indole-substituted 4H-chromenes. This multicomponent reaction imparts very high atom economy (94%) and low environmental factor (0.13).
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spelling pubmed-66456682019-08-27 Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes Bahuguna, Ashish Choudhary, Priyanka Chhabra, Tripti Krishnan, Venkata ACS Omega [Image: see text] A nanocomposite of polyaniline with graphitic carbon nitride (GCN) nanosheets has been synthesized by a facile oxidative polymerization of an aniline monomer and GCN to demonstrate its potential to catalyze the synthesis of various indole-substituted 4H-chromenes. The synthesized nanocomposite was thoroughly characterized using different spectroscopic techniques to confirm the morphology and composition. Subsequently, the fabricated nanocomposite was used as a heterogeneous catalyst to synthesize several bioactive indole-substituted 4H-chromenes in an aqueous medium. Organic transformation under benign and environmentally sustainable conditions is of paramount importance in the view of growing environmental pollution. Water is the universal Green solvent and has been a preferred choice of nature to perform various reactions. The catalyst developed in this work showed very good recyclability and adaptability for the synthesis of various medicinally significant indole-substituted 4H-chromenes. This multicomponent reaction imparts very high atom economy (94%) and low environmental factor (0.13). American Chemical Society 2018-09-27 /pmc/articles/PMC6645668/ /pubmed/31459291 http://dx.doi.org/10.1021/acsomega.8b01687 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Bahuguna, Ashish
Choudhary, Priyanka
Chhabra, Tripti
Krishnan, Venkata
Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes
title Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes
title_full Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes
title_fullStr Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes
title_full_unstemmed Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes
title_short Ammonia-Doped Polyaniline–Graphitic Carbon Nitride Nanocomposite as a Heterogeneous Green Catalyst for Synthesis of Indole-Substituted 4H-Chromenes
title_sort ammonia-doped polyaniline–graphitic carbon nitride nanocomposite as a heterogeneous green catalyst for synthesis of indole-substituted 4h-chromenes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6645668/
https://www.ncbi.nlm.nih.gov/pubmed/31459291
http://dx.doi.org/10.1021/acsomega.8b01687
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