Computational Study of the Ni-Catalyzed C–H Oxidative Cycloaddition of Aromatic Amides with Alkynes

[Image: see text] The mechanism of Ni-catalyzed ortho C(sp(2))–H oxidative cycloaddition of aromatic amides with internal alkynes containing 2-pyridinylmethylamine directing group was investigated using density functional theory (DFT) calculations. The C–H cleavage step proceeds via σ-complex-assist...

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Detalles Bibliográficos
Autores principales: Omer, Humair M., Liu, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648058/
https://www.ncbi.nlm.nih.gov/pubmed/31459693
http://dx.doi.org/10.1021/acsomega.9b00030

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648058/
https://www.ncbi.nlm.nih.gov/pubmed/31459693
http://dx.doi.org/10.1021/acsomega.9b00030

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