Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites

[Image: see text] A direct and efficient Mn(III) acetate-mediated phosphorylation of 2H-indazoles with dialkyl phosphites has been achieved under mild reaction conditions. A series of phosphorylated products with a wide range of functional groups were obtained in moderate to good yields. A radical m...

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Detalles Bibliográficos
Autores principales: Ghosh, Payel, Mondal, Susmita, Hajra, Alakananda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648136/
https://www.ncbi.nlm.nih.gov/pubmed/31459992
http://dx.doi.org/10.1021/acsomega.9b01121
Descripción
Sumario:[Image: see text] A direct and efficient Mn(III) acetate-mediated phosphorylation of 2H-indazoles with dialkyl phosphites has been achieved under mild reaction conditions. A series of phosphorylated products with a wide range of functional groups were obtained in moderate to good yields. A radical mechanism has been proposed for the present protocol.

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