Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites

[Image: see text] A direct and efficient Mn(III) acetate-mediated phosphorylation of 2H-indazoles with dialkyl phosphites has been achieved under mild reaction conditions. A series of phosphorylated products with a wide range of functional groups were obtained in moderate to good yields. A radical m...

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Autores principales: Ghosh, Payel, Mondal, Susmita, Hajra, Alakananda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648136/
https://www.ncbi.nlm.nih.gov/pubmed/31459992
http://dx.doi.org/10.1021/acsomega.9b01121
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author Ghosh, Payel
Mondal, Susmita
Hajra, Alakananda
author_facet Ghosh, Payel
Mondal, Susmita
Hajra, Alakananda
author_sort Ghosh, Payel
collection PubMed
description [Image: see text] A direct and efficient Mn(III) acetate-mediated phosphorylation of 2H-indazoles with dialkyl phosphites has been achieved under mild reaction conditions. A series of phosphorylated products with a wide range of functional groups were obtained in moderate to good yields. A radical mechanism has been proposed for the present protocol.
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spelling pubmed-66481362019-08-27 Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites Ghosh, Payel Mondal, Susmita Hajra, Alakananda ACS Omega [Image: see text] A direct and efficient Mn(III) acetate-mediated phosphorylation of 2H-indazoles with dialkyl phosphites has been achieved under mild reaction conditions. A series of phosphorylated products with a wide range of functional groups were obtained in moderate to good yields. A radical mechanism has been proposed for the present protocol. American Chemical Society 2019-05-23 /pmc/articles/PMC6648136/ /pubmed/31459992 http://dx.doi.org/10.1021/acsomega.9b01121 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Ghosh, Payel
Mondal, Susmita
Hajra, Alakananda
Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites
title Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites
title_full Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites
title_fullStr Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites
title_full_unstemmed Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites
title_short Mn(III)-Mediated C–H Phosphorylation of Indazoles with Dialkyl Phosphites
title_sort mn(iii)-mediated c–h phosphorylation of indazoles with dialkyl phosphites
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648136/
https://www.ncbi.nlm.nih.gov/pubmed/31459992
http://dx.doi.org/10.1021/acsomega.9b01121
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