Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association

[Image: see text] A mild and efficient amination of arenes with azodicarboxylates using potassium bisulfate (KHSO(4)) as the catalyst in 1,1,1,3,3,3-hexafluoro-2-propanol has been developed. This protocol allowed the amination of a broad range of arenes leading to corresponding hydrazides in good to...

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Autores principales: Tang, Ren-Jin, Retailleau, Pascal, Milcent, Thierry, Crousse, Benoit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648143/
https://www.ncbi.nlm.nih.gov/pubmed/31459984
http://dx.doi.org/10.1021/acsomega.9b00781
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author Tang, Ren-Jin
Retailleau, Pascal
Milcent, Thierry
Crousse, Benoit
author_facet Tang, Ren-Jin
Retailleau, Pascal
Milcent, Thierry
Crousse, Benoit
author_sort Tang, Ren-Jin
collection PubMed
description [Image: see text] A mild and efficient amination of arenes with azodicarboxylates using potassium bisulfate (KHSO(4)) as the catalyst in 1,1,1,3,3,3-hexafluoro-2-propanol has been developed. This protocol allowed the amination of a broad range of arenes leading to corresponding hydrazides in good to excellent yields.
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spelling pubmed-66481432019-08-27 Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association Tang, Ren-Jin Retailleau, Pascal Milcent, Thierry Crousse, Benoit ACS Omega [Image: see text] A mild and efficient amination of arenes with azodicarboxylates using potassium bisulfate (KHSO(4)) as the catalyst in 1,1,1,3,3,3-hexafluoro-2-propanol has been developed. This protocol allowed the amination of a broad range of arenes leading to corresponding hydrazides in good to excellent yields. American Chemical Society 2019-05-22 /pmc/articles/PMC6648143/ /pubmed/31459984 http://dx.doi.org/10.1021/acsomega.9b00781 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Tang, Ren-Jin
Retailleau, Pascal
Milcent, Thierry
Crousse, Benoit
Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association
title Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association
title_full Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association
title_fullStr Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association
title_full_unstemmed Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association
title_short Direct Amination of Arenes with Azodicarboxylates Catalyzed by Bisulfate Salt/HFIP Association
title_sort direct amination of arenes with azodicarboxylates catalyzed by bisulfate salt/hfip association
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648143/
https://www.ncbi.nlm.nih.gov/pubmed/31459984
http://dx.doi.org/10.1021/acsomega.9b00781
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