DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes

[Image: see text] 1,8-Diazabicyclo[5.4.0]undec-7-ene-mediated reactions of α-nitroketones with α-cyano-enones and α,β-unsaturated α-ketoesters have been developed. The products, namely, dihydrofurans and conjugated dienes, were isolated in moderate to good yields, and a range of substitutions were t...

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Autores principales: Sahoo, Subas Chandra, Maity, Rajendra, Pan, Subhas Chandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648157/
https://www.ncbi.nlm.nih.gov/pubmed/31459511
http://dx.doi.org/10.1021/acsomega.8b03651
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author Sahoo, Subas Chandra
Maity, Rajendra
Pan, Subhas Chandra
author_facet Sahoo, Subas Chandra
Maity, Rajendra
Pan, Subhas Chandra
author_sort Sahoo, Subas Chandra
collection PubMed
description [Image: see text] 1,8-Diazabicyclo[5.4.0]undec-7-ene-mediated reactions of α-nitroketones with α-cyano-enones and α,β-unsaturated α-ketoesters have been developed. The products, namely, dihydrofurans and conjugated dienes, were isolated in moderate to good yields, and a range of substitutions were tolerated.
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spelling pubmed-66481572019-08-27 DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes Sahoo, Subas Chandra Maity, Rajendra Pan, Subhas Chandra ACS Omega [Image: see text] 1,8-Diazabicyclo[5.4.0]undec-7-ene-mediated reactions of α-nitroketones with α-cyano-enones and α,β-unsaturated α-ketoesters have been developed. The products, namely, dihydrofurans and conjugated dienes, were isolated in moderate to good yields, and a range of substitutions were tolerated. American Chemical Society 2019-02-06 /pmc/articles/PMC6648157/ /pubmed/31459511 http://dx.doi.org/10.1021/acsomega.8b03651 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Sahoo, Subas Chandra
Maity, Rajendra
Pan, Subhas Chandra
DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes
title DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes
title_full DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes
title_fullStr DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes
title_full_unstemmed DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes
title_short DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes
title_sort dbu-mediated addition of α-nitroketones to α-cyano-enones and α,β-unsaturated α-ketoesters: synthesis of dihydrofurans and conjugated dienes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648157/
https://www.ncbi.nlm.nih.gov/pubmed/31459511
http://dx.doi.org/10.1021/acsomega.8b03651
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