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Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients

[Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosi...

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Detalles Bibliográficos
Autores principales: Won, You-Yeon, Ramkrishna, Doraiswami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648224/
https://www.ncbi.nlm.nih.gov/pubmed/31460222
http://dx.doi.org/10.1021/acsomega.9b00736
Descripción
Sumario:[Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosity inside the derivative operator, that is, in one-dimensional rectilinear situations, [Image: see text], [Image: see text], and [Image: see text]. We present simple derivations of these formulas in which diffusive mass transfer, conductive heat transfer, and molecular momentum transfer processes are described using lattice random walk models. We also present simple examples demonstrating how these modifications affect calculations.