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Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
[Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosi...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648224/ https://www.ncbi.nlm.nih.gov/pubmed/31460222 http://dx.doi.org/10.1021/acsomega.9b00736 |
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author | Won, You-Yeon Ramkrishna, Doraiswami |
author_facet | Won, You-Yeon Ramkrishna, Doraiswami |
author_sort | Won, You-Yeon |
collection | PubMed |
description | [Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosity inside the derivative operator, that is, in one-dimensional rectilinear situations, [Image: see text], [Image: see text], and [Image: see text]. We present simple derivations of these formulas in which diffusive mass transfer, conductive heat transfer, and molecular momentum transfer processes are described using lattice random walk models. We also present simple examples demonstrating how these modifications affect calculations. |
format | Online Article Text |
id | pubmed-6648224 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66482242019-08-27 Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients Won, You-Yeon Ramkrishna, Doraiswami ACS Omega [Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosity inside the derivative operator, that is, in one-dimensional rectilinear situations, [Image: see text], [Image: see text], and [Image: see text]. We present simple derivations of these formulas in which diffusive mass transfer, conductive heat transfer, and molecular momentum transfer processes are described using lattice random walk models. We also present simple examples demonstrating how these modifications affect calculations. American Chemical Society 2019-06-27 /pmc/articles/PMC6648224/ /pubmed/31460222 http://dx.doi.org/10.1021/acsomega.9b00736 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Won, You-Yeon Ramkrishna, Doraiswami Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients |
title | Revised Formulation of Fick’s,
Fourier’s,
and Newton’s Laws for Spatially Varying Linear Transport Coefficients |
title_full | Revised Formulation of Fick’s,
Fourier’s,
and Newton’s Laws for Spatially Varying Linear Transport Coefficients |
title_fullStr | Revised Formulation of Fick’s,
Fourier’s,
and Newton’s Laws for Spatially Varying Linear Transport Coefficients |
title_full_unstemmed | Revised Formulation of Fick’s,
Fourier’s,
and Newton’s Laws for Spatially Varying Linear Transport Coefficients |
title_short | Revised Formulation of Fick’s,
Fourier’s,
and Newton’s Laws for Spatially Varying Linear Transport Coefficients |
title_sort | revised formulation of fick’s,
fourier’s,
and newton’s laws for spatially varying linear transport coefficients |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648224/ https://www.ncbi.nlm.nih.gov/pubmed/31460222 http://dx.doi.org/10.1021/acsomega.9b00736 |
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