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Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients

[Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosi...

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Autores principales: Won, You-Yeon, Ramkrishna, Doraiswami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648224/
https://www.ncbi.nlm.nih.gov/pubmed/31460222
http://dx.doi.org/10.1021/acsomega.9b00736
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author Won, You-Yeon
Ramkrishna, Doraiswami
author_facet Won, You-Yeon
Ramkrishna, Doraiswami
author_sort Won, You-Yeon
collection PubMed
description [Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosity inside the derivative operator, that is, in one-dimensional rectilinear situations, [Image: see text], [Image: see text], and [Image: see text]. We present simple derivations of these formulas in which diffusive mass transfer, conductive heat transfer, and molecular momentum transfer processes are described using lattice random walk models. We also present simple examples demonstrating how these modifications affect calculations.
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spelling pubmed-66482242019-08-27 Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients Won, You-Yeon Ramkrishna, Doraiswami ACS Omega [Image: see text] We argue that for situations involving spatially varying linear transport coefficients (diffusivities, thermal conductivities, and viscosities), the original Fick’s, Fourier’s, and Newton’s law equations should be modified to place the diffusivity, thermal conductivity, and viscosity inside the derivative operator, that is, in one-dimensional rectilinear situations, [Image: see text], [Image: see text], and [Image: see text]. We present simple derivations of these formulas in which diffusive mass transfer, conductive heat transfer, and molecular momentum transfer processes are described using lattice random walk models. We also present simple examples demonstrating how these modifications affect calculations. American Chemical Society 2019-06-27 /pmc/articles/PMC6648224/ /pubmed/31460222 http://dx.doi.org/10.1021/acsomega.9b00736 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Won, You-Yeon
Ramkrishna, Doraiswami
Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
title Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
title_full Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
title_fullStr Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
title_full_unstemmed Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
title_short Revised Formulation of Fick’s, Fourier’s, and Newton’s Laws for Spatially Varying Linear Transport Coefficients
title_sort revised formulation of fick’s, fourier’s, and newton’s laws for spatially varying linear transport coefficients
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648224/
https://www.ncbi.nlm.nih.gov/pubmed/31460222
http://dx.doi.org/10.1021/acsomega.9b00736
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