Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF

[Image: see text] Novel ring-opening reactions are achieved employing benzofuroxan as a new type of iminating or aminating reagent. These diverse transformations give access to three types of molecular scaffolds, N-aryl dimethylsulfoximines, methanesulfonamides, and hemiaminal ethers, which are impo...

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Autores principales: Chen, Zhengwang, Liu, Botao, Liang, Pei, Luo, Haiqing, Zheng, Jing, Wen, Xiaowei, Liu, Tanggao, Luo, Guotian, Ye, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648239/
https://www.ncbi.nlm.nih.gov/pubmed/31459330
http://dx.doi.org/10.1021/acsomega.8b03353
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author Chen, Zhengwang
Liu, Botao
Liang, Pei
Luo, Haiqing
Zheng, Jing
Wen, Xiaowei
Liu, Tanggao
Luo, Guotian
Ye, Min
author_facet Chen, Zhengwang
Liu, Botao
Liang, Pei
Luo, Haiqing
Zheng, Jing
Wen, Xiaowei
Liu, Tanggao
Luo, Guotian
Ye, Min
author_sort Chen, Zhengwang
collection PubMed
description [Image: see text] Novel ring-opening reactions are achieved employing benzofuroxan as a new type of iminating or aminating reagent. These diverse transformations give access to three types of molecular scaffolds, N-aryl dimethylsulfoximines, methanesulfonamides, and hemiaminal ethers, which are important structural motifs in organic and medicinal chemistry. The procedures feature solvent-involved reactions, easily available starting materials, operational simplicity, high atom economy, and the potential further transformation of nitro group.
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spelling pubmed-66482392019-08-27 Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF Chen, Zhengwang Liu, Botao Liang, Pei Luo, Haiqing Zheng, Jing Wen, Xiaowei Liu, Tanggao Luo, Guotian Ye, Min ACS Omega [Image: see text] Novel ring-opening reactions are achieved employing benzofuroxan as a new type of iminating or aminating reagent. These diverse transformations give access to three types of molecular scaffolds, N-aryl dimethylsulfoximines, methanesulfonamides, and hemiaminal ethers, which are important structural motifs in organic and medicinal chemistry. The procedures feature solvent-involved reactions, easily available starting materials, operational simplicity, high atom economy, and the potential further transformation of nitro group. American Chemical Society 2019-01-04 /pmc/articles/PMC6648239/ /pubmed/31459330 http://dx.doi.org/10.1021/acsomega.8b03353 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Chen, Zhengwang
Liu, Botao
Liang, Pei
Luo, Haiqing
Zheng, Jing
Wen, Xiaowei
Liu, Tanggao
Luo, Guotian
Ye, Min
Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF
title Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF
title_full Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF
title_fullStr Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF
title_full_unstemmed Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF
title_short Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF
title_sort construction of n–s and c–n bonds from reactions of benzofuroxans with dmso or thf
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648239/
https://www.ncbi.nlm.nih.gov/pubmed/31459330
http://dx.doi.org/10.1021/acsomega.8b03353
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