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FeCl(2)-Mediated Rearrangement of Allylic Alcohols

[Image: see text] A mild, one-pot procedure to produce 3-substituted allylic alcohols from α,β-unsaturated ketones is described. The addition of an organolithium nucleophile produces a tertiary allylic alcohol as an intermediate, which undergoes a 1,3-OH-migration assisted by FeCl(2). The proposed m...

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Detalles Bibliográficos
Autores principales:	Oppong-Quaicoe, Anita A., DeBoef, Brenton
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648291/ https://www.ncbi.nlm.nih.gov/pubmed/31459755 http://dx.doi.org/10.1021/acsomega.9b00163

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