Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization

[Image: see text] High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations rang...

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Autores principales: Mejia, Aurora, Rodriguez, Laurent, Schmitt, Charlène, Andreu, Nathalie, Favéro, Cedrick, Braun, Olivier, Dupuis, Guillaume, Deniau, Elise, Reynaud, Stéphanie, Grassl, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648298/
https://www.ncbi.nlm.nih.gov/pubmed/31460210
http://dx.doi.org/10.1021/acsomega.9b00975
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author Mejia, Aurora
Rodriguez, Laurent
Schmitt, Charlène
Andreu, Nathalie
Favéro, Cedrick
Braun, Olivier
Dupuis, Guillaume
Deniau, Elise
Reynaud, Stéphanie
Grassl, Bruno
author_facet Mejia, Aurora
Rodriguez, Laurent
Schmitt, Charlène
Andreu, Nathalie
Favéro, Cedrick
Braun, Olivier
Dupuis, Guillaume
Deniau, Elise
Reynaud, Stéphanie
Grassl, Bruno
author_sort Mejia, Aurora
collection PubMed
description [Image: see text] High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations ranging from 2.0 to 3.47 M have been successfully tested while keeping the control of the molar masses up to 5 × 10(6) g mol(–1). The products have been characterized in terms of molecular mass and viscosimetric properties.
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spelling pubmed-66482982019-08-27 Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization Mejia, Aurora Rodriguez, Laurent Schmitt, Charlène Andreu, Nathalie Favéro, Cedrick Braun, Olivier Dupuis, Guillaume Deniau, Elise Reynaud, Stéphanie Grassl, Bruno ACS Omega [Image: see text] High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations ranging from 2.0 to 3.47 M have been successfully tested while keeping the control of the molar masses up to 5 × 10(6) g mol(–1). The products have been characterized in terms of molecular mass and viscosimetric properties. American Chemical Society 2019-06-25 /pmc/articles/PMC6648298/ /pubmed/31460210 http://dx.doi.org/10.1021/acsomega.9b00975 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Mejia, Aurora
Rodriguez, Laurent
Schmitt, Charlène
Andreu, Nathalie
Favéro, Cedrick
Braun, Olivier
Dupuis, Guillaume
Deniau, Elise
Reynaud, Stéphanie
Grassl, Bruno
Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization
title Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization
title_full Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization
title_fullStr Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization
title_full_unstemmed Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization
title_short Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization
title_sort synthesis and viscosimetric behavior of poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) obtained by conventional and adiabatic gel process via raft/madix polymerization
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648298/
https://www.ncbi.nlm.nih.gov/pubmed/31460210
http://dx.doi.org/10.1021/acsomega.9b00975
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