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Role of NiMo Alloy and Ni Species in the Performance of NiMo/Alumina Catalysts for Hydrodeoxygenation of Stearic Acid: A Kinetic Study

[Image: see text] The hydrodeoxygenation (HDO) of vegetable oil and fatty acid is extremely important for the sustainable production of diesel-range hydrocarbons. The present work depicts the role of Ni/Mo (mole) in the performance of alumina-supported NiMo catalysts for the HDO of stearic acid. Bot...

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Detalles Bibliográficos
Autores principales: Kumar, Pankaj, Maity, Sunil K., Shee, Debaprasad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648365/
https://www.ncbi.nlm.nih.gov/pubmed/31459514
http://dx.doi.org/10.1021/acsomega.8b03592
Descripción
Sumario:[Image: see text] The hydrodeoxygenation (HDO) of vegetable oil and fatty acid is extremely important for the sustainable production of diesel-range hydrocarbons. The present work depicts the role of Ni/Mo (mole) in the performance of alumina-supported NiMo catalysts for the HDO of stearic acid. Both Ni and NiMo alloy coexist in the NiMo catalysts depending on the Ni and Mo content. With increasing Ni/Mo (mole), the NiMo alloy content in the catalyst increases with the simultaneous decrease in the Ni content. The activity of NiMo catalysts thus enhances with increasing Ni/Mo (mole). The reaction follows a decarbonylation route over Ni sites and a HDO route over NiMo alloy species. C(17) and C(18) alkanes are thus observed as the dominating hydrocarbon product over Ni and NiMo alloy-rich catalysts, respectively. The activity of the NiMo catalyst further enhances with increasing reaction temperature and metal (Ni + Mo) loading. The selectivity to alkanes was, however, not affected by metal loading. A suitable kinetic model was further established based on the reaction mechanism to relate the kinetic data.