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Optical Stability of 1,1′-Binaphthyl Derivatives
[Image: see text] The racemization process of various 1,1′-binaphthyl derivatives is studied by quantum calculations. The preferred racemization pathway passes through a transition state belonging to the C(i) symmetry group. The energy barrier for this process is independent of solvation, the electr...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648391/ https://www.ncbi.nlm.nih.gov/pubmed/31459752 http://dx.doi.org/10.1021/acsomega.9b00619 |