Defect-Assisted Broad-Band Photosensitivity with High Responsivity in Au/Self-Seeded TiO(2) NR/Au-Based Back-to-Back Schottky Junctions

[Image: see text] TiO(2) nanorods (NRs) have generated much interest for both fundamental understanding of defect formation and technological applications in energy harvesting, optoelectronics, and catalysis. Herein, we have grown TiO(2) NR films on glass substrates using a self-seeded approach and annealed them in H(2) ambient to modify their surface defects. It has been shown that broad-band photosensing properties of Au/self-seeded TiO(2) NR/Au-based two back-to-back Schottky junctions (SJs) for a broad wavelength of light are much superior as compared to those of the pristine and the control samples. Photoresponsivity values for the H(2)-annealed sample are 0.42, 0.71, 0.07, and 0.08 A/W for detecting, respectively, 350, 400, 470, and 570 nm lights. Very low dark current and high photocurrent lead to a gain value as high as 1.85 × 10(4) for 400 nm light. Unprecedentedly modified NR-based SJs show excellent photoresponsivity for detecting as low as 25, 36, 48, and 28 μW/cm(2) power densities of 350, 400, 470, and 570 nm lights, respectively. It is found that Ti(3+) defects play a key role in an efficient photoelectron transfer from TiO(2) to Au. Our work, for the first time, highlights the simplicity and reveals the rationale behind the excellent properties of Au/self-seeded TiO(2) NR film/Au back-to-back SJs.