Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols

[Image: see text] The first example of metal-free oxidative hydrolysis of hydrido-siloxanes is reported. Both base-catalyzed and organocatalytic hydrolysis methods are demonstrated to transform 1,3-dihydrido-disiloxanes into 1,3-disiloxanediols. The first example of a chemoselective silane hydrolysi...

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Autores principales: Kelly, Austin T., Franz, Annaliese K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648610/
https://www.ncbi.nlm.nih.gov/pubmed/31459769
http://dx.doi.org/10.1021/acsomega.9b00121
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author Kelly, Austin T.
Franz, Annaliese K.
author_facet Kelly, Austin T.
Franz, Annaliese K.
author_sort Kelly, Austin T.
collection PubMed
description [Image: see text] The first example of metal-free oxidative hydrolysis of hydrido-siloxanes is reported. Both base-catalyzed and organocatalytic hydrolysis methods are demonstrated to transform 1,3-dihydrido-disiloxanes into 1,3-disiloxanediols. The first example of a chemoselective silane hydrolysis is demonstrated.
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spelling pubmed-66486102019-08-27 Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols Kelly, Austin T. Franz, Annaliese K. ACS Omega [Image: see text] The first example of metal-free oxidative hydrolysis of hydrido-siloxanes is reported. Both base-catalyzed and organocatalytic hydrolysis methods are demonstrated to transform 1,3-dihydrido-disiloxanes into 1,3-disiloxanediols. The first example of a chemoselective silane hydrolysis is demonstrated. American Chemical Society 2019-04-04 /pmc/articles/PMC6648610/ /pubmed/31459769 http://dx.doi.org/10.1021/acsomega.9b00121 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Kelly, Austin T.
Franz, Annaliese K.
Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
title Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
title_full Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
title_fullStr Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
title_full_unstemmed Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
title_short Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
title_sort metal-free synthesis of 1,3-disiloxanediols and aryl siloxanols
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648610/
https://www.ncbi.nlm.nih.gov/pubmed/31459769
http://dx.doi.org/10.1021/acsomega.9b00121
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