Cargando…

Metal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols

[Image: see text] The first example of metal-free oxidative hydrolysis of hydrido-siloxanes is reported. Both base-catalyzed and organocatalytic hydrolysis methods are demonstrated to transform 1,3-dihydrido-disiloxanes into 1,3-disiloxanediols. The first example of a chemoselective silane hydrolysi...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kelly, Austin T., Franz, Annaliese K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648610/ https://www.ncbi.nlm.nih.gov/pubmed/31459769 http://dx.doi.org/10.1021/acsomega.9b00121

Ejemplares similares

Transition-metal-free synthesis of aryl 1-thioglycosides with arynes at room temperature
por: Liu, Yao, et al.
Publicado: (2021)

Metal-free C–H arylation of imidazoheterocycles with aryl hydrazines
por: Jana, Sourav, et al.
Publicado: (2018)

Metal-free synthesis of biarenes via photoextrusion in di(tri)aryl phosphates
por: Qrareya, Hisham, et al.
Publicado: (2020)

A mild and metal-free synthesis of 2- and 1-alkyl/aryl/dialkyl-aminoquinolines and isoquinolines
por: Nanaji, Yerramsetti, et al.
Publicado: (2020)

Synthesis of reactive 1,3-diphenyl-6-aryl-substituted fulvene chromophores
por: Budy, Stephen M., et al.
Publicado: (2018)

Metal-Free Synthesis of Aryltriphenylphosphonium Bromides by the Reaction of Triphenylphosphine with Aryl Bromides in Refluxing Phenol
por: Huang, Wenhua, et al.
Publicado: (2019)

Solvent- and transition metal-free amide synthesis from phenyl esters and aryl amines
por: Rzhevskiy, Sergey A., et al.
Publicado: (2019)

Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce–Smiles Rearrangement
por: Holden, Catherine M., et al.
Publicado: (2016)

Programmable synthesis of multiply arylated cubanes through C–H metalation and arylation
por: Okude, Ryo, et al.
Publicado: (2020)

Transition Metal Catalyzed Synthesis of Aryl Sulfides
por: Eichman, Chad C., et al.
Publicado: (2011)

Room Temperature, Metal-Free Arylation of Aliphatic Alcohols
por: Ghosh, Raju, et al.
Publicado: (2014)

Metal‐Free Radical Borylation of Alkyl and Aryl Iodides
por: Cheng, Ying, et al.
Publicado: (2018)

Tetrabutylammonium Bromide-Promoted Metal-Free, Efficient, Rapid, and Scalable Synthesis of N-Aryl Amines
por: Johnson, Chad R., et al.
Publicado: (2018)

Metal‐Free and Open‐Air Arylation Reactions of Diaryliodonium Salts for DNA‐Encoded Library Synthesis
por: Xu, Hongtao, et al.
Publicado: (2022)

One-pot and metal-free synthesis of 3-arylated-4-nitrophenols via polyfunctionalized cyclohexanones from β-nitrostyrenes
por: Asahara, Haruyasu, et al.
Publicado: (2020)

Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement
por: Zhou, Bo, et al.
Publicado: (2019)

Metal-free and solvent-free synthesis of m-terphenyls through tandem cyclocondensation of aryl methyl ketones with triethyl orthoformate
por: Xiao, Xiaoqin, et al.
Publicado: (2020)

Transition-metal-catalyzed synthesis of phenols and aryl thiols
por: Liu, Yajun, et al.
Publicado: (2017)

Aqueous Synthesis of 1-H-2-Substituted Benzimidazoles via Transition-Metal-Free Intramolecular Amination of Aryl Iodides
por: Chen, Chunxia, et al.
Publicado: (2012)

Metal‐Free Aryl Cross‐Coupling Directed by Traceless Linkers
por: Haensch, Veit G., et al.
Publicado: (2019)

Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via S(H)2 Reaction of Aryl Radicals on Tellurium
por: Yamamoto, Yuki, et al.
Publicado: (2022)

Transition-Metal Catalyst Free Oxidative Radical Arylation of N-Methylpyrrole
por: Kocaoğlu, Esma, et al.
Publicado: (2017)

Metal-free electrochemical fluorodecarboxylation of aryloxyacetic acids to fluoromethyl aryl ethers
por: Berger, Michael, et al.
Publicado: (2020)

Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
por: Mao, Shuai, et al.
Publicado: (2022)

Metal-Free S-Arylation of Phosphorothioate Diesters and Related Compounds with Diaryliodonium Salts
por: Sarkar, Sudeep, et al.
Publicado: (2023)

A novel application of 2-silylated 1,3-dithiolanes for the synthesis of aryl/hetaryl-substituted ethenes and dibenzofulvenes
por: Mlostoń, Grzegorz, et al.
Publicado: (2017)

Palladium-Catalyzed α-Arylation of Cyclic β-Dicarbonyl Compounds for the Synthesis of Ca(V)1.3 Inhibitors
por: Yun, Jisu, et al.
Publicado: (2022)

Three-component reaction of azulene, aryl glyoxal and 1,3-dicarbonyl compound for the synthesis of various azulene derivatives
por: Gong, Jing, et al.
Publicado: (2020)

Crystal structures of a series of 6-aryl-1,3-diphenylfulvenes
por: Peloquin, Andrew J., et al.
Publicado: (2019)

4-Dimethylaminopyridine-Catalyzed Metal-Free Aerobic Oxidation of Aryl α-Halo Esters to Aryl α-Keto Esters
por: Jung, Yeonghun, et al.
Publicado: (2020)

Transition Metal-Free Synthesis of Halobenzo[b]furans from O-Aryl Carbamates via o-Lithiation Reactions †
por: Feberero, Claudia, et al.
Publicado: (2022)

One-Pot Metal-Free Synthesis of 3-CF(3)-1,3-Oxazinopyridines by Reaction of Pyridines with CF(3)CO-Acetylenes
por: Muzalevskiy, Vasiliy M., et al.
Publicado: (2019)

Microwave assisted solvent free synthesis of 1,3-diphenylpropenones
por: Kakati, Dwipen, et al.
Publicado: (2011)

Transition Metal‐Free N‐Arylation of Amino Acid Esters with Diaryliodonium Salts
por: Kervefors, Gabriella, et al.
Publicado: (2021)

Transition‐Metal‐Free Coupling of Polyfluorinated Arenes and Functionalized, Masked Aryl Nucleophiles
por: Finck, Lucie, et al.
Publicado: (2021)

OSU-6: A Highly Efficient, Metal-Free, Heterogeneous Catalyst for the Click Synthesis of 5-Benzyl and 5-Aryl-1H-tetrazoles
por: Nammalwar, Baskar, et al.
Publicado: (2015)

Synthesis of 4-aryl-3,4-dihydrocoumarins and 4-aryl-4H-chromenes via Er(OTf)(3)-catalyzed cascade reactions of p-quinone methides with 1,3-dicarbonyl compounds
por: Bao, Xiaobo, et al.
Publicado: (2023)

Metal‐Free and Open‐Air Arylation Reactions of Diaryliodonium Salts for DNA‐Encoded Library Synthesis (Adv. Sci. 26/2022)
por: Xu, Hongtao, et al.
Publicado: (2022)

Facile Synthesis of 3-Arylindenes by HMPA-Promoted Direct Arylation of Indenes with Aryl Fluorides
por: Ji, Xinfei, et al.
Publicado: (2018)

Efficient synthesis of 1,3-diaryl-4-halo-1H-pyrazoles from 3-arylsydnones and 2-aryl-1,1-dihalo-1-alkenes
por: Yang, Yiwen, et al.
Publicado: (2011)

Cannot write session to /tmp/vufind_sessions/sess_leqrfhutbiimt6m1q16q04af7f