Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube

[Image: see text] A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal–organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a syn-conformation of ligands is a thermodynamically favored stable product than a one-dime...

Descripción completa

Detalles Bibliográficos
Autores principales: Xue, Hui, Cao, Junze, Zhao, Liang, Hao, Haigang, Hong, Maochun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648636/
https://www.ncbi.nlm.nih.gov/pubmed/31460173
http://dx.doi.org/10.1021/acsomega.9b01344
_version_ 1783437915105263616
author Xue, Hui
Cao, Junze
Zhao, Liang
Hao, Haigang
Hong, Maochun
author_facet Xue, Hui
Cao, Junze
Zhao, Liang
Hao, Haigang
Hong, Maochun
author_sort Xue, Hui
collection PubMed
description [Image: see text] A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal–organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a syn-conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal–organic double nanotube. In addition, a discrete M(6)L(8)-type cage has also been in situ self-assembled from rationally selected building blocks.
format Online
Article
Text
id pubmed-6648636
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-66486362019-08-27 Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube Xue, Hui Cao, Junze Zhao, Liang Hao, Haigang Hong, Maochun ACS Omega [Image: see text] A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal–organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a syn-conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal–organic double nanotube. In addition, a discrete M(6)L(8)-type cage has also been in situ self-assembled from rationally selected building blocks. American Chemical Society 2019-06-20 /pmc/articles/PMC6648636/ /pubmed/31460173 http://dx.doi.org/10.1021/acsomega.9b01344 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Xue, Hui
Cao, Junze
Zhao, Liang
Hao, Haigang
Hong, Maochun
Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube
title Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube
title_full Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube
title_fullStr Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube
title_full_unstemmed Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube
title_short Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube
title_sort conformation-driven self-assembly: from a 1d metal–organic polymer to an infinite double nanotube
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648636/
https://www.ncbi.nlm.nih.gov/pubmed/31460173
http://dx.doi.org/10.1021/acsomega.9b01344
work_keys_str_mv AT xuehui conformationdrivenselfassemblyfroma1dmetalorganicpolymertoaninfinitedoublenanotube
AT caojunze conformationdrivenselfassemblyfroma1dmetalorganicpolymertoaninfinitedoublenanotube
AT zhaoliang conformationdrivenselfassemblyfroma1dmetalorganicpolymertoaninfinitedoublenanotube
AT haohaigang conformationdrivenselfassemblyfroma1dmetalorganicpolymertoaninfinitedoublenanotube
AT hongmaochun conformationdrivenselfassemblyfroma1dmetalorganicpolymertoaninfinitedoublenanotube

Ejemplares similares