Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles

[Image: see text] A green modification has been introduced to the synthesis of benzothiazoles by using polymethylhydrosiloxane (PMHS) for successive steps of benzotriazole ring cleavage and cyclization, an approach which was previously developed in our lab by the use of n-Bu(3)SnH. The use of the si...

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Autores principales: Yadav, Mangal S., Singh, Anoop S., Agrahari, Anand K., Mishra, Nidhi, Tiwari, Vinod K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648665/
https://www.ncbi.nlm.nih.gov/pubmed/31459794
http://dx.doi.org/10.1021/acsomega.9b00343
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author Yadav, Mangal S.
Singh, Anoop S.
Agrahari, Anand K.
Mishra, Nidhi
Tiwari, Vinod K.
author_facet Yadav, Mangal S.
Singh, Anoop S.
Agrahari, Anand K.
Mishra, Nidhi
Tiwari, Vinod K.
author_sort Yadav, Mangal S.
collection PubMed
description [Image: see text] A green modification has been introduced to the synthesis of benzothiazoles by using polymethylhydrosiloxane (PMHS) for successive steps of benzotriazole ring cleavage and cyclization, an approach which was previously developed in our lab by the use of n-Bu(3)SnH. The use of the silicone industry byproduct PMHS makes this protocol a cost-effective and nontoxic one and thus may be considered for the industrial importance.
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spelling pubmed-66486652019-08-27 Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles Yadav, Mangal S. Singh, Anoop S. Agrahari, Anand K. Mishra, Nidhi Tiwari, Vinod K. ACS Omega [Image: see text] A green modification has been introduced to the synthesis of benzothiazoles by using polymethylhydrosiloxane (PMHS) for successive steps of benzotriazole ring cleavage and cyclization, an approach which was previously developed in our lab by the use of n-Bu(3)SnH. The use of the silicone industry byproduct PMHS makes this protocol a cost-effective and nontoxic one and thus may be considered for the industrial importance. American Chemical Society 2019-04-11 /pmc/articles/PMC6648665/ /pubmed/31459794 http://dx.doi.org/10.1021/acsomega.9b00343 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Yadav, Mangal S.
Singh, Anoop S.
Agrahari, Anand K.
Mishra, Nidhi
Tiwari, Vinod K.
Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles
title Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles
title_full Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles
title_fullStr Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles
title_full_unstemmed Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles
title_short Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles
title_sort silicon industry waste polymethylhydrosiloxane-mediated benzotriazole ring cleavage: a practical and green synthesis of diverse benzothiazoles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648665/
https://www.ncbi.nlm.nih.gov/pubmed/31459794
http://dx.doi.org/10.1021/acsomega.9b00343
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