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Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates

[Image: see text] This short essay urges the community of those who study electrocatalysis and photocatalysis to report measures of the number of active sites in heterogeneous catalysts (especially the redox sites in an electrocatalyst) and the number of photons involved in photoconversions. An exam...

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Detalles Bibliográficos
Autor principal: Weber, Robert S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648758/
https://www.ncbi.nlm.nih.gov/pubmed/31459620
http://dx.doi.org/10.1021/acsomega.8b03377
Descripción
Sumario:[Image: see text] This short essay urges the community of those who study electrocatalysis and photocatalysis to report measures of the number of active sites in heterogeneous catalysts (especially the redox sites in an electrocatalyst) and the number of photons involved in photoconversions. An example of the former is the use of CO stripping for catalysts containing platinum-group metals and N(2)O titration to count redox sites in supported electrocatalysts containing base metals that do not strongly chemisorb CO or hydrogen. A minimal example of the latter is to report energy density as a way to bridge between batch photolysis and flow photoinitiated reactions.