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Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates

[Image: see text] This short essay urges the community of those who study electrocatalysis and photocatalysis to report measures of the number of active sites in heterogeneous catalysts (especially the redox sites in an electrocatalyst) and the number of photons involved in photoconversions. An exam...

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Autor principal: Weber, Robert S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648758/
https://www.ncbi.nlm.nih.gov/pubmed/31459620
http://dx.doi.org/10.1021/acsomega.8b03377
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author Weber, Robert S.
author_facet Weber, Robert S.
author_sort Weber, Robert S.
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description [Image: see text] This short essay urges the community of those who study electrocatalysis and photocatalysis to report measures of the number of active sites in heterogeneous catalysts (especially the redox sites in an electrocatalyst) and the number of photons involved in photoconversions. An example of the former is the use of CO stripping for catalysts containing platinum-group metals and N(2)O titration to count redox sites in supported electrocatalysts containing base metals that do not strongly chemisorb CO or hydrogen. A minimal example of the latter is to report energy density as a way to bridge between batch photolysis and flow photoinitiated reactions.
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spelling pubmed-66487582019-08-27 Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates Weber, Robert S. ACS Omega [Image: see text] This short essay urges the community of those who study electrocatalysis and photocatalysis to report measures of the number of active sites in heterogeneous catalysts (especially the redox sites in an electrocatalyst) and the number of photons involved in photoconversions. An example of the former is the use of CO stripping for catalysts containing platinum-group metals and N(2)O titration to count redox sites in supported electrocatalysts containing base metals that do not strongly chemisorb CO or hydrogen. A minimal example of the latter is to report energy density as a way to bridge between batch photolysis and flow photoinitiated reactions. American Chemical Society 2019-02-22 /pmc/articles/PMC6648758/ /pubmed/31459620 http://dx.doi.org/10.1021/acsomega.8b03377 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Weber, Robert S.
Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates
title Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates
title_full Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates
title_fullStr Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates
title_full_unstemmed Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates
title_short Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates
title_sort normalizing hetereogeneous electrocatalytic and photocatalytic rates
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648758/
https://www.ncbi.nlm.nih.gov/pubmed/31459620
http://dx.doi.org/10.1021/acsomega.8b03377
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