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Resolving the Ultrafast Changes of Chemically Inequivalent Metal–Ligand Bonds in Photoexcited Molecular Complexes with Transient X-ray Absorption Spectroscopy

[Image: see text] Photoactive transition-metal complexes that incorporate heteroleptic ligands present a first coordination shell, which is asymmetric. Although it is generally expected that the metal–ligand bond lengths respond differently to photoexcitation, resolving these fine structural changes...

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Detalles Bibliográficos
Autores principales: Zhang, Jianxin, Zhang, Xiaoyi, Suarez-Alcantara, Karina, Jennings, Guy, Kurtz, Charles A., Lawson Daku, Latévi Max, Canton, Sophie E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648759/
https://www.ncbi.nlm.nih.gov/pubmed/31459775
http://dx.doi.org/10.1021/acsomega.8b03688