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Photoluminescent Oxygeneous-Graphitic Carbon Nitride Nanodot-Incorporated Bioderived Hyperbranched Polyurethane Nanocomposite with Anticounterfeiting Attribute

[Image: see text] Anticounterfeiting materials are neo-advanced materials with utility in covert and security strategies. In this context, a photoluminescent, mechanically robust, and thermally stable hyperbranched polyurethane (PU) nanocomposite was fabricated with oxygeneous-graphitic carbon nitri...

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Detalles Bibliográficos
Autores principales: Bayan, Rajarshi, Karak, Niranjan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648796/
https://www.ncbi.nlm.nih.gov/pubmed/31460011
http://dx.doi.org/10.1021/acsomega.9b00891
Descripción
Sumario:[Image: see text] Anticounterfeiting materials are neo-advanced materials with utility in covert and security strategies. In this context, a photoluminescent, mechanically robust, and thermally stable hyperbranched polyurethane (PU) nanocomposite was fabricated with oxygeneous-graphitic carbon nitride nanodots. The nanocomposite was characterized using infrared, ultraviolet–visible, and photoluminescence spectroscopy, X-ray diffractometry, transmission electron microscopy, and thermogravimetric analysis. The processed nanocomposite demonstrated improved physico-mechanical stability as well as enhanced thermal stability than the pristine PU. The nanocomposite displayed remarkable photoluminescence under long ultraviolet light (365 nm), courtesy of dispersion of oxygeneous-carbon nitride nanodots in the polymer matrix, without any solid-state quenching. The nanocomposite was consequently employed as an ultraviolet light-detectable anticounterfeiting ink material having reinforcing ability.