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Iodine-Mediated Oxidative Rearrangement of α,β-Unsaturated Diaryl Ketones: A Facile Access to 1,2-Diaryl Diketones
[Image: see text] A metal-free oxidative rearrangement was explored for the synthesis of 1,2-diaryl diketones by utilizing α,β-unsaturated diaryl ketones and I(2)/TBHP in good to high yields. The reaction proceeds via oxidative aryl migration, followed by C–C bond cleavage. A simple and high-yieldin...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648810/ https://www.ncbi.nlm.nih.gov/pubmed/31460054 http://dx.doi.org/10.1021/acsomega.9b00833 |