Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media

Anionic lipid amphiphiles with [Ru(II)(bpy)(3)](2+) complex have been prepared. The metal complexes have been found to form ribbon and tape structures depending on chemical structures of lipid amphiphiles. Especially, the composites showed hypochromic effect and induced circular dichroism in organic...

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Autores principales: Hatakeda, Miho, Toohara, Souta, Nakashima, Takuya, Sakurai, Shinichi, Kuroiwa, Keita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6650996/
https://www.ncbi.nlm.nih.gov/pubmed/31277518
http://dx.doi.org/10.3390/ijms20133298
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author Hatakeda, Miho
Toohara, Souta
Nakashima, Takuya
Sakurai, Shinichi
Kuroiwa, Keita
author_facet Hatakeda, Miho
Toohara, Souta
Nakashima, Takuya
Sakurai, Shinichi
Kuroiwa, Keita
author_sort Hatakeda, Miho
collection PubMed
description Anionic lipid amphiphiles with [Ru(II)(bpy)(3)](2+) complex have been prepared. The metal complexes have been found to form ribbon and tape structures depending on chemical structures of lipid amphiphiles. Especially, the composites showed hypochromic effect and induced circular dichroism in organic media, and flexibly and weakly supramolecular control of morphological and optical properties have been demonstrated.
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spelling pubmed-66509962019-08-07 Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media Hatakeda, Miho Toohara, Souta Nakashima, Takuya Sakurai, Shinichi Kuroiwa, Keita Int J Mol Sci Article Anionic lipid amphiphiles with [Ru(II)(bpy)(3)](2+) complex have been prepared. The metal complexes have been found to form ribbon and tape structures depending on chemical structures of lipid amphiphiles. Especially, the composites showed hypochromic effect and induced circular dichroism in organic media, and flexibly and weakly supramolecular control of morphological and optical properties have been demonstrated. MDPI 2019-07-04 /pmc/articles/PMC6650996/ /pubmed/31277518 http://dx.doi.org/10.3390/ijms20133298 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Hatakeda, Miho
Toohara, Souta
Nakashima, Takuya
Sakurai, Shinichi
Kuroiwa, Keita
Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
title Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
title_full Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
title_fullStr Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
title_full_unstemmed Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
title_short Helical-Ribbon and Tape Formation of Lipid Packaged [Ru(bpy)(3)](2+) Complexes in Organic Media
title_sort helical-ribbon and tape formation of lipid packaged [ru(bpy)(3)](2+) complexes in organic media
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6650996/
https://www.ncbi.nlm.nih.gov/pubmed/31277518
http://dx.doi.org/10.3390/ijms20133298
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