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Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution

The extract of honeycomb waste was studied as a corrosion inhibitor on 304 stainless steel in H(2)SO(4) solutions. The honeycomb waste was obtained from beekeeping at Lawang-Malang, East Java, Indonesia. Electrochemical and scanning electron microscopy methods were used to investigate the performanc...

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Autores principales: Gapsari, Femiana, Madurani, Kartika A., Simanjuntak, Firman Mangasa, Andoko, Andoko, Wijaya, Hastono, Kurniawan, Fredy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6651481/
https://www.ncbi.nlm.nih.gov/pubmed/31266233
http://dx.doi.org/10.3390/ma12132120
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author Gapsari, Femiana
Madurani, Kartika A.
Simanjuntak, Firman Mangasa
Andoko, Andoko
Wijaya, Hastono
Kurniawan, Fredy
author_facet Gapsari, Femiana
Madurani, Kartika A.
Simanjuntak, Firman Mangasa
Andoko, Andoko
Wijaya, Hastono
Kurniawan, Fredy
author_sort Gapsari, Femiana
collection PubMed
description The extract of honeycomb waste was studied as a corrosion inhibitor on 304 stainless steel in H(2)SO(4) solutions. The honeycomb waste was obtained from beekeeping at Lawang-Malang, East Java, Indonesia. Electrochemical and scanning electron microscopy methods were used to investigate the performance of the corrosion inhibition process. The inhibition efficiency of the inhibitor (2000 mg/L) reached 97.29% in 0.5 M H(2)SO(4) and decreased with the acid concentration. Kinetic parameters were calculated to explain the effect of acid concentration on the inhibition process. The study on the adsorption behavior of the extracts followed the Frumkin isotherm model. The adsorption of the inhibitor on the 304 stainless steel surface was confirmed by the negative and lower values of Gibbs free energy. The obtained scanning electron microscopy (SEM) images were confirmed by comparing the surface of the specimens with and without inhibitor after corroding for one week. The results indicated that the extract acted as a good inhibitor for 304 stainless steel in acid corrosion.
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spelling pubmed-66514812019-08-08 Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution Gapsari, Femiana Madurani, Kartika A. Simanjuntak, Firman Mangasa Andoko, Andoko Wijaya, Hastono Kurniawan, Fredy Materials (Basel) Article The extract of honeycomb waste was studied as a corrosion inhibitor on 304 stainless steel in H(2)SO(4) solutions. The honeycomb waste was obtained from beekeeping at Lawang-Malang, East Java, Indonesia. Electrochemical and scanning electron microscopy methods were used to investigate the performance of the corrosion inhibition process. The inhibition efficiency of the inhibitor (2000 mg/L) reached 97.29% in 0.5 M H(2)SO(4) and decreased with the acid concentration. Kinetic parameters were calculated to explain the effect of acid concentration on the inhibition process. The study on the adsorption behavior of the extracts followed the Frumkin isotherm model. The adsorption of the inhibitor on the 304 stainless steel surface was confirmed by the negative and lower values of Gibbs free energy. The obtained scanning electron microscopy (SEM) images were confirmed by comparing the surface of the specimens with and without inhibitor after corroding for one week. The results indicated that the extract acted as a good inhibitor for 304 stainless steel in acid corrosion. MDPI 2019-07-01 /pmc/articles/PMC6651481/ /pubmed/31266233 http://dx.doi.org/10.3390/ma12132120 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Gapsari, Femiana
Madurani, Kartika A.
Simanjuntak, Firman Mangasa
Andoko, Andoko
Wijaya, Hastono
Kurniawan, Fredy
Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution
title Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution
title_full Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution
title_fullStr Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution
title_full_unstemmed Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution
title_short Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution
title_sort corrosion inhibition of honeycomb waste extracts for 304 stainless steel in sulfuric acid solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6651481/
https://www.ncbi.nlm.nih.gov/pubmed/31266233
http://dx.doi.org/10.3390/ma12132120
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