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Crystal structure of dimethyl N,N′-[(ethyne-1,2-di­yl)bis­(1,4-phenyl­enecarbon­yl)]bis­(l-alaninate)

The di­phenyl­ethyne unit of the title mol­ecule, C(24)H(24)N(2)O(6), deviates slightly from planarity. The l-alanine moieties adopt distorted helical conformations of opposite winding direction. Infinite ribbons of N—H⋯O=C-connected mol­ecules represent the basic supra­molecular entities of the cry...

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Detalles Bibliográficos
Autores principales: Eissmann, Frank, Seichter, Wilhelm, Weber, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658949/
https://www.ncbi.nlm.nih.gov/pubmed/31391959
http://dx.doi.org/10.1107/S2056989019005826
Descripción
Sumario:The di­phenyl­ethyne unit of the title mol­ecule, C(24)H(24)N(2)O(6), deviates slightly from planarity. The l-alanine moieties adopt distorted helical conformations of opposite winding direction. Infinite ribbons of N—H⋯O=C-connected mol­ecules represent the basic supra­molecular entities of the crystal structure. These aggregates are linked by C—H⋯O hydrogen bonds involving the oxygen atoms of the methyl carboxyl­ate units. The crystal studied was refined as an inversion twin.