Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]

In the title compound, [Cd(2)(C(6)H(9)N(3)O(2))(2)Cl(6)], the coordination polyhedra around the Cd(II) cations are distorted trigonal bipyramids. Two of the chloride ions (one axial and one equatorial) are bridging to the other metal atom, leading to a Cd⋯Cd separation of 3.9162 (4) Å. The O atom of...

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Autores principales: Mohamedi, Nacira, Elleuch, Slim, Boufas, Sihem, Legouira, Messaoud, Djazi, Faiçal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658965/
https://www.ncbi.nlm.nih.gov/pubmed/31391974
http://dx.doi.org/10.1107/S205698901900690X
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author Mohamedi, Nacira
Elleuch, Slim
Boufas, Sihem
Legouira, Messaoud
Djazi, Faiçal
author_facet Mohamedi, Nacira
Elleuch, Slim
Boufas, Sihem
Legouira, Messaoud
Djazi, Faiçal
author_sort Mohamedi, Nacira
collection PubMed
description In the title compound, [Cd(2)(C(6)H(9)N(3)O(2))(2)Cl(6)], the coordination polyhedra around the Cd(II) cations are distorted trigonal bipyramids. Two of the chloride ions (one axial and one equatorial) are bridging to the other metal atom, leading to a Cd⋯Cd separation of 3.9162 (4) Å. The O atom of the l-histidinium cation lies in an axial site. In the crystal, numerous N—H⋯Cl, N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network. Theoretical calculations and spectroscopic data are available as supporting information.
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spelling pubmed-66589652019-08-07 Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)] Mohamedi, Nacira Elleuch, Slim Boufas, Sihem Legouira, Messaoud Djazi, Faiçal Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cd(2)(C(6)H(9)N(3)O(2))(2)Cl(6)], the coordination polyhedra around the Cd(II) cations are distorted trigonal bipyramids. Two of the chloride ions (one axial and one equatorial) are bridging to the other metal atom, leading to a Cd⋯Cd separation of 3.9162 (4) Å. The O atom of the l-histidinium cation lies in an axial site. In the crystal, numerous N—H⋯Cl, N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network. Theoretical calculations and spectroscopic data are available as supporting information. International Union of Crystallography 2019-05-17 /pmc/articles/PMC6658965/ /pubmed/31391974 http://dx.doi.org/10.1107/S205698901900690X Text en © Mohamedi et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Mohamedi, Nacira
Elleuch, Slim
Boufas, Sihem
Legouira, Messaoud
Djazi, Faiçal
Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]
title Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]
title_full Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]
title_fullStr Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]
title_full_unstemmed Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]
title_short Crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κO)cadmium(II)]
title_sort crystal structure of di-μ-chlorido-bis­[di­chlorido(l-histidinium-κo)cadmium(ii)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658965/
https://www.ncbi.nlm.nih.gov/pubmed/31391974
http://dx.doi.org/10.1107/S205698901900690X
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