Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate

The title compound, [Ni(C(10)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·2H(2)O, crystallizes as a racemic mixture in the monoclinic space group C2/c. In the crystal, the 1,1,3,3-tetracyano-2-ethoxypropenide anions and the water molecules are linked by O—H⋯N hydrogen bonds, forming chains running along the [010...

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Autores principales: Chi-Duran, Ignacio, Setifi, Zouaoui, Setifi, Fatima, Jelsch, Christian, Morgenstern, Bernd, Vega, Andres, Herrera, Felipe, Pratap Singh, Dinesh, Hegetschweiler, Kaspar, Boyaala, Rabab
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658966/
https://www.ncbi.nlm.nih.gov/pubmed/31391984
http://dx.doi.org/10.1107/S2056989019006959
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author Chi-Duran, Ignacio
Setifi, Zouaoui
Setifi, Fatima
Jelsch, Christian
Morgenstern, Bernd
Vega, Andres
Herrera, Felipe
Pratap Singh, Dinesh
Hegetschweiler, Kaspar
Boyaala, Rabab
author_facet Chi-Duran, Ignacio
Setifi, Zouaoui
Setifi, Fatima
Jelsch, Christian
Morgenstern, Bernd
Vega, Andres
Herrera, Felipe
Pratap Singh, Dinesh
Hegetschweiler, Kaspar
Boyaala, Rabab
author_sort Chi-Duran, Ignacio
collection PubMed
description The title compound, [Ni(C(10)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·2H(2)O, crystallizes as a racemic mixture in the monoclinic space group C2/c. In the crystal, the 1,1,3,3-tetracyano-2-ethoxypropenide anions and the water molecules are linked by O—H⋯N hydrogen bonds, forming chains running along the [010] direction. The bpy ligands of the cation are linked to the chain via C—H⋯π(cation) inter­actions involving the CH(3) group. The inter­molecular inter­actions were investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots.
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spelling pubmed-66589662019-08-07 Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate Chi-Duran, Ignacio Setifi, Zouaoui Setifi, Fatima Jelsch, Christian Morgenstern, Bernd Vega, Andres Herrera, Felipe Pratap Singh, Dinesh Hegetschweiler, Kaspar Boyaala, Rabab Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Ni(C(10)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·2H(2)O, crystallizes as a racemic mixture in the monoclinic space group C2/c. In the crystal, the 1,1,3,3-tetracyano-2-ethoxypropenide anions and the water molecules are linked by O—H⋯N hydrogen bonds, forming chains running along the [010] direction. The bpy ligands of the cation are linked to the chain via C—H⋯π(cation) inter­actions involving the CH(3) group. The inter­molecular inter­actions were investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots. International Union of Crystallography 2019-05-24 /pmc/articles/PMC6658966/ /pubmed/31391984 http://dx.doi.org/10.1107/S2056989019006959 Text en © Chi-Duran et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Chi-Duran, Ignacio
Setifi, Zouaoui
Setifi, Fatima
Jelsch, Christian
Morgenstern, Bernd
Vega, Andres
Herrera, Felipe
Pratap Singh, Dinesh
Hegetschweiler, Kaspar
Boyaala, Rabab
Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
title Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
title_full Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
title_fullStr Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
title_short Crystal structure and Hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
title_sort crystal structure and hirshfeld surface analysis of tris­(2,2′-bi­pyridine)­nickel(ii) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658966/
https://www.ncbi.nlm.nih.gov/pubmed/31391984
http://dx.doi.org/10.1107/S2056989019006959
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