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Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne

The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four mol­ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol­ecule with the three cyclic moieties arranged in a line. The mol­ecules in the unit cell pack in a parallel fashi...

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Detalles Bibliográficos
Autores principales: Hofstetter, Robert, Elvers, Benedict J., Potlitz, Felix, Link, Andreas, Schulzke, Carola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658967/
https://www.ncbi.nlm.nih.gov/pubmed/31391988
http://dx.doi.org/10.1107/S2056989019007138
Descripción
Sumario:The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four mol­ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol­ecule with the three cyclic moieties arranged in a line. The mol­ecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S(3) fragment and the C—H of a cyclo­hexyl group from a glide-related mol­ecule [C⋯S = 3.787 (2) Å].