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Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane
The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four molecules in the unit cell. In the crystal, the asymmetric unit comprises the entire molecule with the three cyclic moieties arranged in a line. The molecules in the unit cell pack in a parallel fashi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658967/ https://www.ncbi.nlm.nih.gov/pubmed/31391988 http://dx.doi.org/10.1107/S2056989019007138 |
Sumario: | The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four molecules in the unit cell. In the crystal, the asymmetric unit comprises the entire molecule with the three cyclic moieties arranged in a line. The molecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S(3) fragment and the C—H of a cyclohexyl group from a glide-related molecule [C⋯S = 3.787 (2) Å]. |
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