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Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane
The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four molecules in the unit cell. In the crystal, the asymmetric unit comprises the entire molecule with the three cyclic moieties arranged in a line. The molecules in the unit cell pack in a parallel fashi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658967/ https://www.ncbi.nlm.nih.gov/pubmed/31391988 http://dx.doi.org/10.1107/S2056989019007138 |
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author | Hofstetter, Robert Elvers, Benedict J. Potlitz, Felix Link, Andreas Schulzke, Carola |
author_facet | Hofstetter, Robert Elvers, Benedict J. Potlitz, Felix Link, Andreas Schulzke, Carola |
author_sort | Hofstetter, Robert |
collection | PubMed |
description | The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four molecules in the unit cell. In the crystal, the asymmetric unit comprises the entire molecule with the three cyclic moieties arranged in a line. The molecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S(3) fragment and the C—H of a cyclohexyl group from a glide-related molecule [C⋯S = 3.787 (2) Å]. |
format | Online Article Text |
id | pubmed-6658967 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-66589672019-08-07 Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane Hofstetter, Robert Elvers, Benedict J. Potlitz, Felix Link, Andreas Schulzke, Carola Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four molecules in the unit cell. In the crystal, the asymmetric unit comprises the entire molecule with the three cyclic moieties arranged in a line. The molecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S(3) fragment and the C—H of a cyclohexyl group from a glide-related molecule [C⋯S = 3.787 (2) Å]. International Union of Crystallography 2019-05-24 /pmc/articles/PMC6658967/ /pubmed/31391988 http://dx.doi.org/10.1107/S2056989019007138 Text en © Hofstetter et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Hofstetter, Robert Elvers, Benedict J. Potlitz, Felix Link, Andreas Schulzke, Carola Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
title | Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
title_full | Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
title_fullStr | Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
title_full_unstemmed | Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
title_short | Crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
title_sort | crystal structure of 7,8,15,16,17-pentathiadispiro[5.2.5(9).3(6)]heptadecane |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658967/ https://www.ncbi.nlm.nih.gov/pubmed/31391988 http://dx.doi.org/10.1107/S2056989019007138 |
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