Cargando…

Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne

The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four mol­ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol­ecule with the three cyclic moieties arranged in a line. The mol­ecules in the unit cell pack in a parallel fashi...

Descripción completa

Detalles Bibliográficos
Autores principales: Hofstetter, Robert, Elvers, Benedict J., Potlitz, Felix, Link, Andreas, Schulzke, Carola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658967/
https://www.ncbi.nlm.nih.gov/pubmed/31391988
http://dx.doi.org/10.1107/S2056989019007138
_version_ 1783439046212583424
author Hofstetter, Robert
Elvers, Benedict J.
Potlitz, Felix
Link, Andreas
Schulzke, Carola
author_facet Hofstetter, Robert
Elvers, Benedict J.
Potlitz, Felix
Link, Andreas
Schulzke, Carola
author_sort Hofstetter, Robert
collection PubMed
description The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four mol­ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol­ecule with the three cyclic moieties arranged in a line. The mol­ecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S(3) fragment and the C—H of a cyclo­hexyl group from a glide-related mol­ecule [C⋯S = 3.787 (2) Å].
format Online
Article
Text
id pubmed-6658967
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-66589672019-08-07 Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne Hofstetter, Robert Elvers, Benedict J. Potlitz, Felix Link, Andreas Schulzke, Carola Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(12)H(20)S(5), crystallizes in the monoclinic space group P2(1)/c with four mol­ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol­ecule with the three cyclic moieties arranged in a line. The mol­ecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S(3) fragment and the C—H of a cyclo­hexyl group from a glide-related mol­ecule [C⋯S = 3.787 (2) Å]. International Union of Crystallography 2019-05-24 /pmc/articles/PMC6658967/ /pubmed/31391988 http://dx.doi.org/10.1107/S2056989019007138 Text en © Hofstetter et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Hofstetter, Robert
Elvers, Benedict J.
Potlitz, Felix
Link, Andreas
Schulzke, Carola
Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
title Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
title_full Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
title_fullStr Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
title_full_unstemmed Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
title_short Crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
title_sort crystal structure of 7,8,15,16,17-penta­thiadi­spiro­[5.2.5(9).3(6)]hepta­deca­ne
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658967/
https://www.ncbi.nlm.nih.gov/pubmed/31391988
http://dx.doi.org/10.1107/S2056989019007138
work_keys_str_mv AT hofstetterrobert crystalstructureof78151617pentathiadispiro525936heptadecane
AT elversbenedictj crystalstructureof78151617pentathiadispiro525936heptadecane
AT potlitzfelix crystalstructureof78151617pentathiadispiro525936heptadecane
AT linkandreas crystalstructureof78151617pentathiadispiro525936heptadecane
AT schulzkecarola crystalstructureof78151617pentathiadispiro525936heptadecane