Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)

In the title 1:1 co-crystal, [Cu(C(24)H(24)N(8)O(6))]·C(11)H(11)N(3)O(4), each of the crystal components forms undulating layers which stack alternately along the b-axis direction. Mol­ecules of the Cu(II) complex are connected via C—H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus...

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Detalles Bibliográficos
Autores principales: Marten, Jan, Seichter, Wilhelm, Weber, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658969/
https://www.ncbi.nlm.nih.gov/pubmed/31391977
http://dx.doi.org/10.1107/S2056989019005838
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author Marten, Jan
Seichter, Wilhelm
Weber, Edwin
author_facet Marten, Jan
Seichter, Wilhelm
Weber, Edwin
author_sort Marten, Jan
collection PubMed
description In the title 1:1 co-crystal, [Cu(C(24)H(24)N(8)O(6))]·C(11)H(11)N(3)O(4), each of the crystal components forms undulating layers which stack alternately along the b-axis direction. Mol­ecules of the Cu(II) complex are connected via C—H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus forming supra­molecular networks. Mol­ecules of the aryl­hydrazone component are linked by C—H⋯O inter­actions into zigzag strands showing no inter­strand association.
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spelling pubmed-66589692019-08-07 Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1) Marten, Jan Seichter, Wilhelm Weber, Edwin Acta Crystallogr E Crystallogr Commun Research Communications In the title 1:1 co-crystal, [Cu(C(24)H(24)N(8)O(6))]·C(11)H(11)N(3)O(4), each of the crystal components forms undulating layers which stack alternately along the b-axis direction. Mol­ecules of the Cu(II) complex are connected via C—H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus forming supra­molecular networks. Mol­ecules of the aryl­hydrazone component are linked by C—H⋯O inter­actions into zigzag strands showing no inter­strand association. International Union of Crystallography 2019-05-21 /pmc/articles/PMC6658969/ /pubmed/31391977 http://dx.doi.org/10.1107/S2056989019005838 Text en © Marten et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Marten, Jan
Seichter, Wilhelm
Weber, Edwin
Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
title Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
title_full Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
title_fullStr Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
title_full_unstemmed Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
title_short Crystal structure of (N,N′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(II)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
title_sort crystal structure of (n,n′-ethyl­enebis{3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]-4-oxo­pentan-2-iminato})copper(ii)–3-[2-(3-nitro­phen­yl)hydrazin-1-yl­idene]pentane-2,4-dione (1/1)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658969/
https://www.ncbi.nlm.nih.gov/pubmed/31391977
http://dx.doi.org/10.1107/S2056989019005838
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AT seichterwilhelm crystalstructureofnnethylenebis323nitrophenylhydrazin1ylidene4oxopentan2iminatocopperii323nitrophenylhydrazin1ylidenepentane24dione11
AT weberedwin crystalstructureofnnethylenebis323nitrophenylhydrazin1ylidene4oxopentan2iminatocopperii323nitrophenylhydrazin1ylidenepentane24dione11

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