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Crystal structure of bis(4-methoxypyridine-κN)(meso-5,10,15,20-tetraphenylporphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
In the crystal structure of the title compound, [Fe(C(44)H(28)N(4))(C(6)H(7)NO)(2)]ClO(4), the Fe(III) ions are coordinated in an octahedral fashion by four N atoms of the porphyrin moiety and two N atoms of two 4-methoxypyridine ligands into discrete complexes that are located on inversion cente...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658977/ https://www.ncbi.nlm.nih.gov/pubmed/31391961 http://dx.doi.org/10.1107/S2056989019006194 |
Sumario: | In the crystal structure of the title compound, [Fe(C(44)H(28)N(4))(C(6)H(7)NO)(2)]ClO(4), the Fe(III) ions are coordinated in an octahedral fashion by four N atoms of the porphyrin moiety and two N atoms of two 4-methoxypyridine ligands into discrete complexes that are located on inversion centers. Charge-balance is achieved by perchlorate anions that are disordered around twofold rotation axes. In the crystal structure, the discrete cationic complexes and the perchlorate anions are arranged into layers with weak C—H⋯O interactions between the cations and the anions. The porphyrin moieties of neighboring layers show a herringbone-like arrangement. |
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